75858-37-6

Upstream product

• 43179-48-2 L-arabinose di(ethylthio)acetal 
• 5328-37-0 L-arabinose 
• 100-39-0 benzyl bromide 
• 74405-35-9 4,5-O-isopropylidene-L-arabinose di(ethylthio)acetal 

Downstream Products

• 75858-28-5 2,3-di-O-benzyl-4,5-O-isopropylidene-aldehydo-L-arabinose 
• 230951-69-6 2,3-di-O-benzyl-L-arabinose di(ethylthio)acetal 
• 75858-29-6 (E)-(5S,6R)-5,6-Bis-benzyloxy-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-hex-2-enoic acid methyl ester 
• 75858-32-1 [2,3-di-O-benzyl-4,6-dideoxy-6-(methoxycarbonyl)-D-gluco-β-C-pyranosyl]methanol 
• 75858-30-9 (E)-(5S,6S,7S)-5,6-Bis-benzyloxy-7,8-dihydroxy-oct-2-enoic acid methyl ester 
• 75858-31-0 (1R,6R,8S,9R)-8,9-Bis-benzyloxy-3,10-dioxa-bicyclo[4.3.1]decan-4-one 
• 406684-06-8 (E)-3-[(1S,2S,3R)-2,3-Bis-benzyloxy-1-(tert-butyl-dimethyl-silanyloxymethyl)-4,4-bis-ethylsulfanyl-butoxy]-acrylic acid methyl ester 

Relevant academic research and scientific papers

Short de novo synthesis of fully functionalized uronic acid monosaccharides

(Chemical Equation Presented) Short and Sweet: A convergent route leads to orthogonally protected D-glucuronic and L-iduronic acid thioglycoside building blocks, commonly used in heparin oligosaccharide assembly (see scheme). Rapid access to substantial q

Cyano/diallylamine additions to glycoside and nucleoside aldehydes and its application to the synthesis of polyoxin L and uracil polyoxin C

Three efficient, high yielding syntheses of precursors (1) of carbamoylpolyoxamic acid from L-arabinose, based on the simultaneous addition of the acid and amine functionalities, are described. Utilizing the same methodology and uridine as the starting ma

Synthesis of ring A of ambruticin and proof of its absolute stereochemistry

Appropriately derivatized ambruticin was converted by reductive ozonolysis to tetrahydropyran 9c and cyclopropane 12a, which were synthesized from L-arabinose and (R)-Feist's acid in an unambiguous manner.