758716-31-3Relevant academic research and scientific papers
An intramolecular Diels-Alder approach to the eunicellins: Enantioselective total syntheses of ophirin B and astrogorgin
Crimmins, Michael T.,Brown, Brandon H.,Plake, Hilary R.
, p. 1371 - 1378 (2007/10/03)
The enantioselective syntheses of the eunicellins ophirin B and astrogorgin have been completed. Ring-closing metatheses provide efficient access to the oxonene rings, and highly diastereoselective intramolecular Diels-Alder reactions resulted in the form
A general strategy for synthesis of both (6Z)- and (6E)-cladiellin diterpenes: Total syntheses of (-)-cladiella-6,11-dien-3-ol, (+)-polyanthellin A, (-)-cladiell-11-ene-3,6,7-triol, and (-)-deacetoxyalcyonin acetate
Kim, Hyoungsu,Lee, Hyunjoo,Kim, Jayoung,Kim, Sanghee,Kim, Deukjoon
, p. 15851 - 15855 (2007/10/03)
The first total synthesis of an (E)-cladiellin diterpene, (-)-cladiella-6,11-diene-3-ol (1), was accomplished featuring an intramolecular amide enolate alkylation-intramolecular Diels-Alder strategy. In addition, a highly stereo-, regio-, and chemoselecti
Ah intramolecular Diels-Alder approach to the eunicelins: Enantioselective total synthesis of ophirin B
Crimmins, Michael T.,Brown, Brandon H.
, p. 10264 - 10266 (2007/10/03)
The enantioselective synthesis of the eunicellin ophirin B has been completed. A ring-closing metathesis provides efficient access to the oxonene ring, and a highly diastereoselective intramolecular Diels-Alder reaction results in the formation of the hyd
