75879-50-4

Upstream product

• 74581-59-2 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-12-oxo-dodeca-5Z-enoate 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 
• 72605-81-3 1,2-O-isopropylidene-3-O-(methylthio)thiocarbonyl-α-D-glucofuranose 
• 2457-93-4 (3aR,5S,6aR)-2,2-dimethyl-5-[(2R)-oxiran-2-yl]-3a,5,6,6a-tetrahydrofuro[2,3-d] [1,3]dioxole 
• 4005-46-3 3-deoxy-1,2-O-isopropylidene-D-glucose 
• 16667-96-2 1,2,5,6-di-O-isopropylidene-α-D-glucofuranose-3-O-(S-methylxanthate) 
• 74707-99-6 5,6-Di-O-acetyl-3-deoxy-1,2-O-isopropylidene-α-D-ribo-hexofuranose 
• 74581-55-8 (R)-8-((3aR,5S,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-ynoic acid methyl ester 
• 74581-56-9 (Z)-(R)-8-((3aR,5S,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-enoic acid methyl ester 
• 74581-57-0 (Z)-(R)-8-(tert-Butyl-diphenyl-silanyloxy)-8-((3aR,5S,6aR)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-oct-5-enoic acid methyl ester 
• 74595-17-8 (Z)-(8R,9S,11R)-8-(tert-Butyl-diphenyl-silanyloxy)-12,12-bis-ethylsulfanyl-9,11-dihydroxy-dodec-5-enoic acid methyl ester 
• 74581-58-1 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-12,12-di(ethylthio)dodeca-5Z-enoate 
• 75824-57-6 5,6-di-O-acetyl-1,2-O-isopropylidene-3-O-(methylthio)thiocarbonyl-α-D-glucofuranose 
• 75879-49-1 (R)-8-((3aR,5S,6aR)-2,2-Dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-8-hydroxy-oct-5-ynoic acid 

Downstream Products

• 93547-88-7 t-butyl diphenylsilanol 
• 75879-51-5 methyl 8R-tert-butyldiphenylsilyloxy-9S,11R-dihydroxy-9,11-O-isopropylidene-eicosa-5Z,12E,14Z-trienoate 

Relevant academic research and scientific papers

Oxidation products of arachidonic acid II. The synthesis of methyl 8R,9S,11R-trihydroxy-5Z,12E,14Z-eicosatrienoate

A stereospecific total synthesis of the title compound, 37, starting from diacetone glucose (9), is described.Key intermediates in the synthesis are 3-deoxy-5,6-anhydro-1,2-O-isopropylidene-glucofuranose (15), obtained in 50percent yield fom 9, and methyl