75908-55-3

Upstream product

• 100-39-0 benzyl bromide 
• 80357-05-7 1,2-benzisothiazol-3-(2H)-thione-1,1-dioxide nitranion sodium salt 

Downstream Products

• 7668-30-6 3-piperidino-1,2-benzoisothiazole 1,1-dioxide 
• 100-53-8 phenylmethanethiol 
• 59456-33-6 ((pentylthio)methyl) benzene 
• 53573-34-5 2,2-dimethylthiopropionic acid S-benzyl ester 
• 538-74-9 dibenzyl sulfide 
• 87156-77-2 C₁₆H₁₆S 
• 19360-96-4 4-benzylsulfanyl-butan-2-one 
• 32362-99-5 benzylthioacetate 
• 18953-26-9 Benzyl 4-thiobutyrate 
• 770-34-3 benzyl(isopropyl)sulfane 
• 16979-50-3 3-benzylsulfanyl-propionaldehyde 
• 54829-40-2 S-benzyl-2-phenylethanethioate 
• 19360-98-6 3-benzylsulfanyl-butanal 

Relevant academic research and scientific papers

An Odorless Preparative Method of Sulfides and Thiocarboxylic S-Esters Using 3-(Alkylthio)-1,2-benzisothiazole 1,1-Dioxide

It was found that sodium salt of 1,2-benzisothiazole-3(2H)-thione 1,1-dioxide (thiosaccharin) readily reacted with alkyl halide affording 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide (3).Treatment of 3 with piperidine produces the corresponding alkanethiol in situ quantitatively and subsequent treatment with various electrophiles gives the corresponding sulfides and thiocarboxylic S-esters in good yields.

SYNTHESIS AND REACTION OF 3-(ALKYLTHIO)-1,2-BENZISOTHIAZOLE 1,1-DIOXIDES AS AN ODORLESS CRYSTALLINE EQUIVALENT OF THIOLS

It was found that sodium salt of 1,2-benzisothiazol-3(2H)-thione 1,1-dioxide (thiosaccharin) readily reacted with alkyl halide affording 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide, which very smoothly produced the corresponding alkanethiol by the reaction with piperidine in almost quantitative yield.