18953-26-9Relevant academic research and scientific papers
Cleavage of S-S bond by Sm/cat. CoCl2 or Sm/cat. CoCl2 · 6H2O system. A novel method for the synthesis of thiolesters
Chen, Rener,Zhang, Yongmin
, p. 3699 - 3704 (1999)
The Sm/cat. CoCl2 or Sm/cat. CoCl2 · 6H2O system promoted dlsulfides to react with anhydrides or acyl chlorides to afford thiolesters in good yields under mild and neutral conditions.
COBALT(II) CHLORIDE CATALYSED COUPLING OF THIOLS AND ANHYDRIDES: A NEW AND EFFICIENT SYNTHESIS OF THIOL ESTERS
Ahmad, Saeed,Iqbal, Javed
, p. 3791 - 3794 (2007/10/02)
Cobalt(II) chloride in acetonitrile catalyses the coupling of anhydrides or acid chlorides with thiols to yield thiol esters in excellent yields.
An Odorless Preparative Method of Sulfides and Thiocarboxylic S-Esters Using 3-(Alkylthio)-1,2-benzisothiazole 1,1-Dioxide
Yamada, Hiroyuki,Kinoshita, Hideki,Inomata, Katsuhiko,Kotake, Hiroshi
, p. 949 - 950 (2007/10/02)
It was found that sodium salt of 1,2-benzisothiazole-3(2H)-thione 1,1-dioxide (thiosaccharin) readily reacted with alkyl halide affording 3-(alkylthio)-1,2-benzisothiazole 1,1-dioxide (3).Treatment of 3 with piperidine produces the corresponding alkanethiol in situ quantitatively and subsequent treatment with various electrophiles gives the corresponding sulfides and thiocarboxylic S-esters in good yields.
