75961-62-5

Basic information

• Product Name: 2-benzyl-4-(carbomethoxy)pyridine
• Synonyms: 2-benzyl-4-(carbomethoxy)pyridine
• CAS NO: 75961-62-5
• Molecular Weight: 227.263
• Mol File: 75961-62-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-benzyl-4-(carbomethoxy)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzyl-4-(carbomethoxy)pyridine(75961-62-5)
• EPA Substance Registry System: 2-benzyl-4-(carbomethoxy)pyridine(75961-62-5)

Safety Data

• Hazardous Substances Data: 75961-62-5(Hazardous Substances Data)

Upstream product

• 3783-38-8 methyl isonicotinate N-oxide 
• 78761-38-3 cinnamyl propionate 
• 58481-11-1 methyl 2-chloroisonicotinate 
• 62673-31-8 benzylzinc(II) bromide 
• 53317-09-2 9-benzyl-9-borabicyclo[3.3.1]nonane 
• 62673-31-8 benzyl(bromo)zinc 
• 110-86-1 pyridine 
• 103-82-2 phenylacetic acid 

Downstream Products

• 1251843-21-6 methyl 2-(cyclohexylmethyl)piperidine-4-carboxylate 
• 1262891-85-9 methyl 2-(3-fluoro-2-methyl-benzyl)-3-formyl-1-phenyl-indolizine-7-carboxylate 
• 1262891-86-0 2-(3-fluoro-2-methyl-benzyl)-7-methoxycarbonyl-1-phenyl-indolizine-3-carboxylic acid 
• 1262891-87-1 3-(4-tert-butoxycarbonyl-piperazine-1-carbonyl)-2-(3-fluoro-2-methyl-benzyl)-1-phenyl-indolizine-7-carboxylic acid methyl ester 
• 1262891-88-2 3-(4-tert-butoxycarbonyl-piperazine-1-carbonyl)-2-(3-fluoro-2-methyl-benzyl)-1-phenyl-indolizine-7-carboxylic acid 
• 1262891-89-3 4-[2-(3-fluoro-2-methyl-benzyl)-7-methylcarbamoyl-1-phenyl-indolizine-3-carbonyl]-piperazine-1-carboxylic acid tert-butyl ester 
• 1262891-84-8 methyl-2-(3-fluoro-2-methyl-benzyl)-1-phenyl-indolizine-7-carboxylate 
• 1251843-22-7 dimethyl 2-(cyclohexylmethyl)piperidine-1,4-dicarboxylate 
• 1251843-23-8 2-(cyclohexylmethyl)-1-(methoxycarbonyl)piperidine-4-carboxylic acid 
• 1251845-92-7 (2S,4S)-methyl 2-(cyclohexylmethyl)-4-(3-oxo-2,3-dihydroisoxazol-5-yl)piperidine-1-carboxylate 

Relevant articles and documents

Photocatalyzed ortho-Alkylation of Pyridine N-Oxides through Alkene Cleavage

A photocatalyzed reaction of pyridine N-oxides with alkenes gives ortho-alkylated pyridines with cleavage of the carbon–carbon double bond. Benzyl and secondary alkyl groups are incorporated at the ortho position of pyridines in one pot.

CYCLIC (AZA)INDOLIZINECARBOXAMIDES, THEIR PREPARATION AND THEIR USE AS PHARMACEUTICALS

The present invention relates to cyclic indolizinecarboxamides and azaindolizinecarboxamides of the formulae Ia and Ib, (Ia) (Ib) wherein R, Ra, R10, R20, R30, R40, Y, n, p and q have the meanings ind

Photochemistry of Stable Pyridinyl Radicals. Photolysis of N-Alkyl-4-(carboalkoxy)pyridinyls

Photoinduced decomposition of N-benzyl-4-carbethoxypyridinyl (1a), N-methyl- (1b) and N-benzyl-4-(carbomethoxy)pyridinyl (1c), and their mixture was studied in degassed acetonitrile.N-benzyl homologues (1a and 1c) were smoothly photolyzed to ethyl (or methyl) isonicotinate by loss of a benzyl group, whereas the N-methyl homologue (1b) was comparatively stable toward UV light; the rate of disappearance of 1c relative to that of 1b was 11:1.A mechanism is postulated, which involves the formation of an alkyl radical by C-N bond homolysis followed by attack on the pyridinyl radical to form dihydropyridines.This is supported by a plot of the yield of ethyl isonicotinate vs. the ratio of initial concentrations 0/0.Pyridinyl radicals 1 possess their absorption maxima at around 300, 395, and 630 nm; those at 300 and 395 nm maxima participate in this reaction.