75983-86-7Relevant academic research and scientific papers
Conjugated addition of cyanotrimethylsilane to α,β-unsaturated ketones
Utimoto, Kiitiro,Obayashi, Michio,Shishiyama, Yuho,Inoue, Masaharu,Nozaki, Hitosi
, p. 3389 - 3392 (1980)
Triethylaluminium-mediated reaction of cyanotrimethylsilane with 6-methylbicyclo[4.4.0]dec-1-en-3-one affords a mixture of diastereomeric 1,4-adducts. The reaction is kinetically controlled in toluene, whereas thermodynamically in refluxing THF. 4-Methyl-
