Tetrahedron Letters p. 3389 - 3392 (1980)
Update date:2022-08-02
Topics:
Utimoto, Kiitiro
Obayashi, Michio
Shishiyama, Yuho
Inoue, Masaharu
Nozaki, Hitosi
Triethylaluminium-mediated reaction of cyanotrimethylsilane with 6-methylbicyclo[4.4.0]dec-1-en-3-one affords a mixture of diastereomeric 1,4-adducts. The reaction is kinetically controlled in toluene, whereas thermodynamically in refluxing THF. 4-Methyl-
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