76003-54-8

Upstream product

• 121393-52-0 C₈H₁₁O₂PS*C₂₃H₂₆N₂O₄ 
• 101-83-7 N-cyclohexyl-cyclohexanamine 
• 172487-18-2 ethyl Phenylphosphinate 
• 6230-93-9 O-ethyl S-hydrogenphenylphosphorothioic acid 
• 6230-64-4 O-Ethyl hydrogen phenylphosphonothioate dicyclohexylammonium salt 
• 121393-53-1 C₈H₁₁O₂PS*C₂₃H₂₆N₂O₄ 
• 644-97-3 Dichlorophenylphosphine 
• 10544-50-0 sulfur 
• 824-72-6 P,P-dichlorophenylphosphine oxide 
• 6230-93-9 O-ethyl phenylphosphonothioic acid 
• 6230-93-9 (-)-O-ethyl-phenyl-thiophosphonic acid 
• 5075-13-8 O-ethyl phenylphosphonochloridothioate 

Downstream Products

• 57557-82-1 O-ethyl, S-n-butyl phenylphosphonothiolate 
• 57557-81-0 O-ethyl S-n-propyl phenylphosphonothioate 
• 57557-80-9 O,S-diethyl phenylphosphonothionate 
• 1351791-00-8 C₁₀H₁₅O₂PS 
• 123278-21-7 S-methyl O-ethyl ohenylphosphonothioate 
• 6230-93-9 O-ethyl S-hydrogenphenylphosphorothioic acid 
• 61733-60-6 (S)-O-ethyl O-methyl phenylphosphonothioate 
• 61733-60-6 (R)-O-ethyl O-methyl phenylphosphonothioate 
• 6230-64-4 (S)-(-)-O-Ethyl hydrogen phenylphosphonothioate dicyclohexylammonium salt 
• 6230-64-4 (R)-(+)-O-Ethyl hydrogen phenylphosphonothioate dicyclohexylammonium salt 
• 102794-05-8 O-ethyl-S-methyl phenylphosphonothioate 
• 1351790-99-2 C₁₀H₁₅O₂PS 
• 102794-05-8 (R)-(+)-O-Ethyl S-methyl phenylphosphonothioate 
• 21722-85-0 phenylphosphonothioic acid S-benzyl ester O-ethyl ester 

Relevant academic research and scientific papers

Phosphonothioate hydrolysis by molybdocene dichlorides: Importance of metal interaction with the sulfur of the thiolate leaving group

The metallocene bis(cyclopentadienyl)molybdenum(IV) dichloride Cp 2MoCl2 hydrolyzes O,S-diethyl phenylphosphonothioate (1) with only P-S scission to yield a phosphonate under mild aqueous conditions. In terms of degrading phosphonoth

Stereochemical inversion of phosphonothioate methanolysis by La(III) and Zn(II): Mechanistic implications for the degradation of organophosphate neurotoxins

The utility of phosphonothioate methanolysis to degrade organophosphate neurotoxins has prompted the stereochemical investigation of this useful transformation. The methanolysis of enantiomerically pure O,S-diethyl phenylphosphonothioate (5) was studied b

Kinetic Facial Selectivity in Nucleophilic Displacements at Tetracoordinate Phosphorus: Kinetics and Stereochemistry in the Reaction of Sodium Ethoxide with O,S-Dimethyl Phenylphosphonothioate

The reaction of ethoxide ion with O,S-dimethyl phenylphosphonothioate (1a) proceeds with competitive displacements of the methylthio and methoxy ligands.Each displacement occurs with complete inversion of configuration.The two products, ethyl methyl pheny

SILICON-PHOSPHORUS ANALOGIES. PARTICIPATION OF EXTERNAL NUCLEOPHILES TO ACTIVATED PROCESSES OF RACEMIZATION AND HYDROLYSIS OF CHLOROPHOSPHONO DERIVATIVES

Kinetic and stereochemical studies show nucleophilic assistance by dimethylformamide (DMF), dimethylacetamide (DMA), hexamethylphosphotriamide (HMPT) and N-methylimidazole (NMI) in racemization and solvolysis of menthylchloro(phenyl)phosphonate, 1a, and O-ethylchloro(phenyl)thiophosphonate, 2.Similar orders of nucleophilic reactivity (Nu = NMI >> HMPT > DMF> DMA), and identical rate laws (vrac = k 2 and vH2O = k') are consistent with a common mechanism, governed by entropy (-60 u.e/= -40 u.e.).Analogies between reaction mechanisms at silicon and phosphorus are clearly evidenced.A two step process, involving rate-determining attack on a pentacoordinate complex is discussed.