7614-96-2Relevant articles and documents
Copper(II) Tetrafluoroborate-Catalyzed Acetylation of Phenols, Thiols, Alcohols, and Amines
Chakraborti, Asit K.,Gulhane, Rajesh,Shivani
, p. 111 - 115 (2007/10/03)
Copper(II) tetrafluoroborate efficiently catalyzes acetylation of structurally diverse phenols, alcohols, thiols, and amines with stoichiometric amounts of Ac2O under solvent-free conditions at room temperature. Acid-sensitive alcohols are smoothly acetylated without competitive side reactions. The reaction is influenced by the steric and electronic factors associated with the substrate as well as the anhydride. Acetylation of a sterically hindered substrate requires excess of anhydride and longer time. Acylation with less electrophilic anhydrides affords poor to moderate yields.
Nucleophilic Reactivity: Nucleophilic Aromatic Substitution Reactions of 2,4-Dinitrochlorobenzene and Picryl Chloride in Aqueous and Methanol Solutions
Gandler, Joseph R.,Setiarahardjo, Irianto U.,Tufon, Chrisanthus,Chen, Chinpan
, p. 4169 - 4173 (2007/10/02)
Rate constants for nucleophilic aromatic substitution reactions of picryl chloride, I, with acetate ion and a series of amine nucleophiles, including primary, secondary, tertiary (quinuclidines), and amines which show the α-effect, in aqueous and methanol
