761402-09-9

Basic information

• Product Name: {1-[3-(methyl-diphenyl-silanyl)-allyl]-2-oxo-2,3,4,7-tetrahydro-1H-azepin-3-yl}-carbamic acid tert-butyl ester
• Synonyms: {1-[3-(methyl-diphenyl-silanyl)-allyl]-2-oxo-2,3,4,7-tetrahydro-1H-azepin-3-yl}-carbamic acid tert-butyl ester
• CAS NO: 761402-09-9
• Molecular Weight: 462.664
• Mol File: 761402-09-9.mol

Chemical Properties

• CAS DataBase Reference: {1-[3-(methyl-diphenyl-silanyl)-allyl]-2-oxo-2,3,4,7-tetrahydro-1H-azepin-3-yl}-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: {1-[3-(methyl-diphenyl-silanyl)-allyl]-2-oxo-2,3,4,7-tetrahydro-1H-azepin-3-yl}-carbamic acid tert-butyl ester(761402-09-9)
• EPA Substance Registry System: {1-[3-(methyl-diphenyl-silanyl)-allyl]-2-oxo-2,3,4,7-tetrahydro-1H-azepin-3-yl}-carbamic acid tert-butyl ester(761402-09-9)

Safety Data

• Hazardous Substances Data: 761402-09-9(Hazardous Substances Data)

Upstream product

• 761401-97-2 Allyl-[(E)-3-(methyl-diphenyl-silanyl)-allyl]-amine 
• 756436-57-4 3-(methyldiphenylsilyl)-2-propyn-1-ol 
• 101844-25-1 3E-(methyldiphenylsilyl)-2-propen-1-ol 
• 119479-32-2 2-((tert-butyloxycarbonyl)amino)-4-pentenoic acid 
• 144-79-6 chloromethyldiphenylsilane 
• 761402-01-1 (1-{allyl-[3-(methyl-diphenyl-silanyl)-allyl]-carbamoyl}-but-3-enyl)-carbamic acid tert-butyl ester 
• 761401-96-1 3E-(methyldiphenylsilyl)-2-propenal 

Relevant articles and documents

Directed ring-closing metathesis of trienes by silyl substitution

A synthetic strategy for 'disarming' a terminal alkene by substitution with a bulky silyl blocking group has been developed. In a series of model studies, sequential selective ring-closing metathesis of trienes followed by selective mono-hydrogenation of the resulting diene is described. The bulky silylated alkene is activated for a subsequent cross-metathesis reaction with a range of diverse alkenes by protodesilylation.