76176-94-8Relevant academic research and scientific papers
Cu-catalyzed oxidative Povarov reactions between N-alkyl N-methylanilines and saturated oxa- and thiacycles
Kawade, Rahul Kisan,Huple, Deepak B.,Lin, Rong-Jing,Liu, Rai-Shung
, p. 6625 - 6628 (2015/04/14)
Cu-catalyzed oxidative Povarov reactions between N,N-dialkylanilines and saturated oxa- or thiacycles with tert-butyl hydroperoxide (TBHP) are described; notably, the reactions use neither [4π] nor [2π]-motifs as the initial reagents. The use of cheap alkane-based substances as building units is of mechanistic and practical interest as two inert sp3 C-H bonds are activated.
Oxidative coupling-type mechanism of N,N-dialkylanilines in solvent-free conditions forming crystal violet derivatives. A clay-mediated and microwave-promoted approach
Lopez-Cortes,Penieres-Carrillo,Ortega-Alfaro,Gutierrez-Perez,Toscano,Alvarez-Toledano
, p. 1299 - 1304 (2007/10/03)
In the clay-mediated reaction of N,N-disubstituted anilines using microwave radiation as an energy source in the absence of solvent, crystal violet and derivatives, diphenylmethanes, and biphenyls were isolated along with intermediates supporting an oxidative coupling-type mechanism.
