762-03-8Relevant academic research and scientific papers
Reactions of halodiazirines with potassium ethyl xanthate
Creary, Xavier
, p. 29 - 32 (2007/10/03)
Aryl halodiazarines are reduced by potassium ethyl xanthate to give benzonitrile as the major product along with significant amounts of a novel heterocyclic product, 3-phenyl-5-ethoxy-1,2,4-thiadiazole. A mechanism involving fragmentation of an N-substituted diazirine is considered.
Synthesis of O-Alkyl Carbonochloridothioates
Martinez, Manuel A.,Vega, Juan C.
, p. 760 - 761 (2007/10/02)
The preparation of O-alkyl carbonochloridothioates (2) was improved by performing the reaction of thiophosgene with potassium alkoxides in the corresponding alcohol or in tetrahydrofuran at -65 deg C for 1 hour.In all cases, the reaction yielded products 2, O,O-dialkyl carbonothioates (4), and dialkyl carbonates (5) in varying distribution.
