76220-89-8

Basic information

• Product Name: 8-bromo-2,2,6-trimethyl-4,4-bis(trifluoromethyl)-1,4-dihydro-2H-3,1-benzoxazine
• CAS NO: 76220-89-8
• Molecular Formula: C₁₃H₁₂BrF₆NO
• Molecular Weight: 392.1349
• Mol File: 76220-89-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 325.3°C at 760 mmHg
• Flash Point: 150.5°C
• Density: 1.515g/cm³
• Vapor Pressure: 0.000232mmHg at 25°C
• Refractive Index: 1.454
• CAS DataBase Reference: 8-bromo-2,2,6-trimethyl-4,4-bis(trifluoromethyl)-1,4-dihydro-2H-3,1-benzoxazine(CAS DataBase Reference)
• NIST Chemistry Reference: 8-bromo-2,2,6-trimethyl-4,4-bis(trifluoromethyl)-1,4-dihydro-2H-3,1-benzoxazine(76220-89-8)
• EPA Substance Registry System: 8-bromo-2,2,6-trimethyl-4,4-bis(trifluoromethyl)-1,4-dihydro-2H-3,1-benzoxazine(76220-89-8)

Safety Data

• Hazardous Substances Data: 76220-89-8(Hazardous Substances Data)

Upstream product

• 80360-40-3 6-bromo-4-methyl-2-<1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl>aniline 
• 67-64-1 acetone 

Downstream Products

• 76220-90-1 4-methyl-2,6-bis<1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl>aniline 
• 80360-43-6 4-methyl-2,6-bis<1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl>iodobenzene 
• 80360-42-5 1,4-dihydro-8-<1-hydroxy-1-(trifluoromethyl)-2,2,2-trifluoroethyl>-6-methyl-2,2-dimethyl-4,4-bis(trifluoromethyl)-2H-<3,1>benzoxazine 

Relevant articles and documents

Tridentate Ligand Useful in Stabilizing Higher Coordination States of Nonmetallic Elements. An Aryldialkoxydifluoroperiodinane

The synthesis of amino diol 2 in several steps from amino alcohol 5 allows the incorporation of the tridentate ligand in a pentacoordinate iodine species.This tridentate ligand provides stability to a hypervalent system due to its various structural features, including the five-membered rings.As a result, difluoroperiodinane 4 is isolated when iodo diol 10 is treated with 2 equiv of bromine trifluoride.This periodinane, which is a strong oxidizing reagent, demonstrated an exceptionally low reactivity.It does, however, rapidly oxidize trimethylchlorosilane or aqueoushydrogen chloride to give chlorine.Oxidation of p-chlorophenyl sulfide by 4 gives a mixture of sulfoxide and sulfone upon hydrolysis.