762287-69-4Relevant academic research and scientific papers
Selective electrochemical glycosylation by reactivity tuning
France, Robert R.,Compton, Richard G.,Davis, Benjamin G.,Fairbanks, Antony J.,Rees, Neil V.,Wadhawan, Jay D.
, p. 2195 - 2202 (2004)
Electrochemical glycosylation of a selenoglycoside donor proceeds efficiently in an undivided cell in acetonitrile to yield β-glycosides. Measurement of cyclic voltammograms for a selection of seleno-, thio-, and O-glycosides indicates the dependence of o
Synthesis and applications of a light-fluorous glycosyl donor
Zhang, Fa,Zhang, Wei,Zhang, Yan,Curran, Dennis P.,Liu, Gang
supporting information; experimental part, p. 2594 - 2597 (2009/08/07)
A new method using a light-fluorous glycosyl donor and an orthogonal tagging strategy to synthesize oligosaccharides and glycoconjugates has been developed. The glycosyl donor orthogonally protected with a C8F 17-Silyl tag and benzoyl groups was reacted with excess amounts of glycosyl acceptor. Fluorous solid-phase extraction separated the glycosylated product and unreacted glycosyl acceptor. This new protocol has high reaction efficiency and easy separation, which was demonstrated in the synthesis of an unprotected trisaccharide and an O-glycosylated serine in this paper.
