76276-13-6Relevant academic research and scientific papers
Triiodoisocyanuric acid: a new and convenient reagent for regioselective coiodination of alkenes and enolethers with oxygenated nucleophiles
Ribeiro, Rodrigo da S.,Esteves, Pierre M.,de Mattos, Marcio C.S.
, p. 8747 - 8751 (2008/03/18)
The reaction of triiodoisocyanuric acid (prepared from I2 and trichloroisocyanuric acid in 90% yield) with alkenes in the presence of oxygenated nucleophilic solvents (alcohols, AcOH and H2O) led to the corresponding β-iodoethers, β-iodoacetates and iodohydrins, in 66-98% isolated yield. Enolethers reacted with triiodoisocyanuric acid in MeOH to produce dialkylacetals (70-83%).
Green alkoxyiodination of cyclohexene mediated by natural clay
Villegas, Raul A. S.,Do Espirito Santo Jr., Jose Luiz,Sanseverino, Antonio M.,De Mattos, Marcio C. S.,De Aguiar, Monica R. M. P.,Guarino, Alcides W. S.
, p. 1627 - 1631 (2007/10/03)
The reaction of cyclohexene with iodine and alcohols (ethanol, isopropanol, and t-butanol) at room temperature is effectively mediated by clays to produce the corresponding trans-β-alkoxy-iodocyclohexane. Copyright Taylor & Francis, Inc.
SYNTHESIS OF β-IODO-t-BUTYL AND METHYL ETHERS FROM THE REACTION OF ALKENES WITH t-BUTYL AND METHYL HYPOIODITES
Glover, Stephen A.,Goosen, Andre
, p. 2005 - 2008 (2007/10/02)
t-Butyl or methyl hypoiodite, generated from potassium t-butoxide or sodium methoxide and iodine monochloride, react with olefins via a bridged iodonium ion intermediate giving the trans-vicinal iodo-t-butyl or -methyl ethers.
