763-98-4Relevant academic research and scientific papers
REACTIONS OF DIALKYL DITHIOPHOSPHORIC AND DIPHENYLDITHIOPHOSPHORIC ACIDS WITH THIOCYANATES
Zimin, M. G.,Kamalov, R. M.,Cherkasov, R. A.,Pudovik, A. N.
, p. 371 - 378 (2007/10/02)
The interaction between phosphorus(IV) dithio acid partial esters and thiocyanates proceeds with initial formation of addition products to the CN bond.These adducts are either split by the second molecule of dithio acid to S-alkyl dithiocarbamates and tetraalkyl trithiophosphates or rearrange into dialkyl N-thiophosphoryldithiocarbamates.The latter easily split off the thiols and convert to isothiocyanatothiophosphates.A number of thiophosphorylated and diphosphorylated thioureas were synthesized by the reaction of isothiocyanatothiophosphates with amines and α-aminoalkylphosphonates.
