76300-72-6

Upstream product

• 7646-78-8 tin(IV) chloride 
• 39767-03-8 tetra(p-biphenylyl)tin 

Downstream Products

• 1050-07-3 di-p-biphenyltin dihydride 
• 79471-50-4 (C₆H₅C₆H₄)2Sn(S₂CN(CH₂)3)2 
• 79471-46-8 bis-p-biphenyltin(IV) N,N-dimethyldithiocarbamate 
• 76270-70-7 bis(2,6-dimethylmorpholinedithiocarbamato)bis(p-biphenyl)tin(IV) 
• 76270-65-0 bis(isopropyl benzyldithiocarbamato)bis(p-biphenyl)tin(IV) 
• 76270-67-2 bis(4-methylpiperidinedithiocarbamato)bis(p-biphenyl)tin(IV) 
• 76270-64-9 bis(ethyl benzyldithiocarbamato)bis(p-biphenyl)tin(IV) 
• 76270-63-8 bis(methyl benzyldithiocarbamato)bis(p-biphenyl)tin(IV) 
• 76270-68-3 bis(4-methylpiperazinedithiocarbamato)bis(p-biphenyl)tin(IV) 
• 106995-69-1 (C₆H₅C₆H₄)2Sn(C₆H₅COCHCOC₆H₅)2 
• 76270-69-4 bis(morpholinedithiocarbamato)bis(p-biphenyl)tin(IV) 
• 107015-80-5 (C₆H₅C₆H₄)2Sn(C₆H₅COCHCOCH₃)2 
• 76270-66-1 bis(piperidinedithiocarbamato)bis(p-biphenyl)tin(IV) 
• 106995-68-0 bis(p-biphenyltin)-bis(acetylacetonate) 

Relevant academic research and scientific papers

Aryltin chlorides and hydrides: Preparation, detailed NMR studies and DFT calculations

A series of novel tin chlorides RnSnCl4-n and respective hydrides RnSnH4-n were synthesized displaying a range of substituted phenyl residues, as well as naphthyl moieties (R = Ph, o-tolyl, 2,4-xylyl, 2,6-xylyl, p-biphenyl, 1-naphthyl, 2-naphthyl). These compounds were characterized using 1H, 13C and 119Sn NMR spectroscopy. In addition, X-ray diffraction was employed to elucidate the molecular structure of all solid aryltin chlorides (8e10, 14, 15). In each case, the tin is in a distorted tetrahedral environment. All naphthyl containing derivatives exhibit displaced π-π stacking. DFT calculations were carried out to compare experimental NMR data with calculated 13C and 119Sn shifts, as well as 13C-119Sn coupling constants.