di-p-biphenyltin dichloride

Base Information

• Chemical Name: di-p-biphenyltin dichloride
• CAS No.: 76300-72-6
• Molecular Formula: C₂₄H₁₈Cl₂Sn
• Molecular Weight: 496.023
• Mol file: 76300-72-6.mol

Synonyms:di-p-biphenyltin dichloride

Chemical Property of di-p-biphenyltin dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of di-p-biphenyltin dichloride

There total 1 articles about di-p-biphenyltin dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

tin(IV) chloride (7646-78-8) + tetra(p-biphenylyl)tin (39767-03-8) → di-p-biphenyltin dichloride (76300-72-6)

Guidance literature:

at 180 ℃; for 2h; Schlenk technique;

DOI:10.1016/j.jorganchem.2013.03.012

Reference yield: 99.0%

di-p-biphenyltin dichloride (76300-72-6) → di-p-biphenyltin dihydride (1050-07-3)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether; at 0 ℃; for 0.0833333h; Schlenk technique;

DOI:10.1016/j.jorganchem.2013.03.012

Reference yield: 90.0%

di-p-biphenyltin dichloride (76300-72-6) + sodium dimethyldithiocarbamate (128-04-1) → bis-p-biphenyltin(IV) N,N-dimethyldithiocarbamate (79471-46-8)

Guidance literature:

In acetone; dropwise addn. of sodium salt to tin dichloride soln. with stirring; keeping at room temp., 30 min; filtration; evapn.; crystn. (petroleum ether/dichloromethane); elem. anal.;

upstream raw materials:

tin(IV) chloride

tetra(p-biphenylyl)tin

Downstream raw materials:

biscinnamatobis(p-biphenyl)tin(IV)

diazidobis(p-biphenyl)tin(IV)

bis-anisylcarboxylatobis(p-biphenyl)tin(IV)