76331-08-3

Basic information

• Product Name: Cyclododecanone, 2-methoxy-
• CAS NO: 76331-08-3
• Molecular Formula: C13H24O2
• Molecular Weight: 212.332
• Mol File: 76331-08-3.mol

Chemical Properties

• CAS DataBase Reference: Cyclododecanone, 2-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclododecanone, 2-methoxy-(76331-08-3)
• EPA Substance Registry System: Cyclododecanone, 2-methoxy-(76331-08-3)

Safety Data

• Hazardous Substances Data: 76331-08-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 69381-33-5 α-iodocyclododecanone 
• 110-00-9 furan 
• 35951-28-1 2-chlorocyclododecanone 

Relevant articles and documents

Photo-cleavage of carbon-carbon bond of α-iodocycloalkanones giving ω,ω-dialkoxyalkanoic ester in alcohol

The irradiation at λ > 300 nm of α-iodocycloalkanones with a high- pressure mercury lamp in alcohols containing a small amount of water afforded the corresponding ω,ω-dialkoxyalkanoic ester (65-88%) by photochemical cleavage of the C(I)-C=O bond at room temperature. In the case of a commercial fluorescent lamp as the irradiating light source, photochemical ring-opening products were also obtained. The irradiation of 2α-iodo-5α- and 4β-iodo-5β-cholestan-3-ones in methanol gave methyl 2,2-dimethoxy-2,3- seco-5α-cholestan-3-oate and methyl 4,4-dimethoxy-3,4-seco-5β-cholestan-3- oate in 78 and 62% yields, respectively. The photochemical behavior of the cleavage reaction of α-iodocycloalkanones is also discussed on the basis of 2-hydroxycycloalkanone as an intermediate.

ERZEUGUNG UND CYCLOADDITION VON ALLYLIUMIONEN AUS α-HALOGENKETONEN UNTER SOLVOLYSE-BEDINGUNGEN

Some α-haloketones react with furan in methanolic solution in the presence of base to form the 3-oxo-8-oxabicyclooct-6-enes (11), the products derived from a cycloaddition of an allylium intermediate (5 or 6).