69381-33-5Relevant articles and documents
Reaction of Enol Silyl Ethers and Enol Acetates with Copper(II) Nitrate-Iodine: Synthesis of α-Iodo Ketones
Cort, Antonella Dalla
, p. 6708 - 6709 (1991)
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Reaction of enol ethers with the I2-H2O2 system: Synthesis of 2-iodo-1-methoxy hydroperoxides and their deperoxidation and demethoxylation to 2-iodo ketones
Terent'ev, Alexander O.,Borisov, Alexander M.,Platonov, Maxim M.,Starikova, Zoya A.,Chernyshev, Vladimir V.,Nikishin, Gennady I.
experimental part, p. 4159 - 4166 (2011/03/18)
The reaction of enol ethers with the I2-H2O 2 system in diethyl ether affords 2-iodo ketones and the previously unknown 2-iodo-1-methoxy hydroperoxides. In the presence of the I 2-H2O2 system, the latter compounds undergo deperoxidation and demethoxylation to form 2-iodo ketones. The reaction conditions were found for the synthesis of 2-iodo ketones from enol ethers in 67-94% yields. Georg Thieme Verlag Stuttgart - New York.
Reaction of Enol Silyl Ethers with Silver Carboxylate-Iodine. Synthesis of α-Acyloxy Carbonyl Compounds
Rubottom, George M.,Mott, Robert C.,Juve, Henrik D.
, p. 2717 - 2721 (2007/10/02)
The sequential treatment of enol silyl ethers with silver carboxylate-iodine (2:1) and then fluoride affords high yields of the corresponding α-acyloxy carbonyl compounds.Thus a wide range of variation is now possible for the acyloxy portion of the molecu
