76355-52-7

Upstream product

• 67-56-1 methanol 
• 825-54-7 cyclopent-1-en-1-ylbenzene 
• 23253-31-8 1-phenyl-6,7,8-trioxa-bicyclo<3.2.1>octane 
• 76355-55-0 3-phenyl-3,7-dimethoxy-1,2-dioxepan 
• 76355-56-1 4-benzoylbutanal dimethylacetal 

Relevant academic research and scientific papers

Ozonolyses of 1-Alkyl-Substituted 3-Methylindenes. Remarkable Effects of the Substituent Steric Bulk and the Stereochemistry of the Carbonyl Oxide Intermediates on the Efficiency of Ozonide Formation

Ozonolyses of 3-methyl- and 3-isopropyl-l-methylindenes (1a,b) in ether gave mainly the corresponding oligomers 3a,b, while in the case of 3-phenyl- and 3-tert-butyl-1-methylindenes (1c,d), the corresponding exo-endo mixtures of ozonides 2c,d were obtaine

Reaction of Ozonides with Methanol in the Presence of Chlorosulphonic Acid: Selective Cleavage of the C-O Bond of the Peroxide Bridge

The reaction of 1,2,4-trioxolans (ozonides) (1) with methanol in the presence of chlorosulphonic acid gives good yields of products formed via the corresponding α-methoxy hydroperoxides.The order of reactivity of the ozonides, as estimated by periodic measurement of the n.m.r. spectra of a mixture of the ozonide and chlorosulphonic acid in CD3OD, is as follows: (1a), (1b) > (1c), (1d), (1e), (1f), (1g) > (1h).