76355-56-1

Upstream product

• 76355-55-0 3-phenyl-3,7-dimethoxy-1,2-dioxepan 
• 176853-29-5 5,5-dimethoxy-5-phenylpentanal dimethyl acetal 
• 67-56-1 methanol 
• 825-54-7 cyclopent-1-en-1-ylbenzene 
• 811-98-3 d⁽⁴⁾-methanol 
• 23253-31-8 1-phenyl-6,7,8-trioxa-bicyclo<3.2.1>octane 
• 77116-24-6 C₁₁H₁₂Cl₅O₃Sb 

Downstream Products

• 107128-83-6 4-[1,3]Dithian-2-yl-1-phenyl-butan-1-one 
• 1501-04-8 Methyl 4-benzoylbutanoate 
• 76355-52-7 1-methoxy-4-benzoylbutyl hydroperoxide 
• 107128-89-2 C₂₁H₂₉NO₂S₂ 
• 107128-85-8 2-(4-Phenyl-pent-4-enyl)-[1,3]dithiane-2-carbaldehyde 
• 107128-84-7 2-(4-Phenyl-pent-4-enyl)-[1,3]dithiane 

Relevant academic research and scientific papers

CAN mediated fragmentation of 1-phenylcycloalkenes: Synthesis of monoacetals of 1,n-dicarbonyl compounds

Phenylcycloalkenes undergo facile oxidative fragmentation in presence of CAN in methanol giving ketoacetals of 1,n-dicarbonyl compounds.

Oxidative fragmentation of 1-aryl-1-cycloalkenes using cerium(IV) ammonium nitrate (CAN): Some novel observations

1-Phenyl-1-cycloalkenes undergo oxidative fragmentation in presence of CAN in methanol, affording 1,n-dicarbonyl compounds as the major products along with 1,2-dimethoxycycloalkanes. The reaction under deoxygenated conditions afforded the latter in good yields. In the presence of azide ion, fragmentation leading to the corresponding cyanoketones was observed whereas with sulfinate only the 1-methoxy-2-sulfonyl cycloalkanes were formed.

A new approach to arylaliphatic 1,5-, 1,6-, and 1,7-dicarbonyl compounds and their monoacetals based on direct anodic oxidation of 1-phenyl- and benzo[c]cycloalkenes

A new simple approach to ω-benzoylalkanals, 2-(ω-formylalkyl)benzaldehydes, and their monoacetals was developed based on direct anodic oxidation of 1-phenylcycloalkenes and benzo[c]cycloalkenes in methanol followed by acid hydrolysis of the electrolysis p

Reaction of Ozonides with Methanol in the Presence of Chlorosulphonic Acid: Selective Cleavage of the C-O Bond of the Peroxide Bridge

The reaction of 1,2,4-trioxolans (ozonides) (1) with methanol in the presence of chlorosulphonic acid gives good yields of products formed via the corresponding α-methoxy hydroperoxides.The order of reactivity of the ozonides, as estimated by periodic measurement of the n.m.r. spectra of a mixture of the ozonide and chlorosulphonic acid in CD3OD, is as follows: (1a), (1b) > (1c), (1d), (1e), (1f), (1g) > (1h).