76358-92-4

Basic information

• Product Name: Pyridine, 2-[(phenylseleno)methyl]-
• CAS NO: 76358-92-4
• Molecular Formula: C12H11NSe
• Molecular Weight: 248.186
• Mol File: 76358-92-4.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: Pyridine, 2-[(phenylseleno)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2-[(phenylseleno)methyl]-(76358-92-4)
• EPA Substance Registry System: Pyridine, 2-[(phenylseleno)methyl]-(76358-92-4)

Safety Data

• Hazardous Substances Data: 76358-92-4(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 1666-13-3 diphenyl diselenide 
• 106966-98-7 potassium 2-(pyridin-2-yl)acetate 
• 43071-19-8 2-[(Dimethylamino)methyl]pyridine 
• 4377-33-7 2-chloromethylpyridine 
• 586-98-1 2-Hydroxymethylpyridine 
• 31106-82-8 2-(bromomethyl)pyridine hydrobromide 
• 109-06-8 α-picoline 
• 5707-04-0 Phenylselenyl chloride 
• 2179-79-5 phenyl selenocyanate 
• 71098-88-9 N-phenylselanylphthalimide 

Downstream Products

• 404361-95-1 Pd(0)(η2-fumaronitrile)(C5H4NCH2SeC6H5) 
• 1268397-94-9 N-methyl 2-(phenylselenomethyl)pyridinium triflate 
• 1441253-24-2 [ruthenium(II)(η⁶-benzene)(chloride)(NC5H4CH2SeC6H5)](hexafluorophosphate) 
• 1370620-98-6 ((C₅(CH₃)5)IrCl(NC₅H₄CH₂SeC₆H₅))⁽¹⁺⁾*PF₆^(1-)=((C₅(CH₃)5)IrCl(NC₅H₄CH₂SeC₆H₅))PF₆ 
• 1206594-85-5 PdCl₂(2-phenylselenomethylpyridine) 
• 78808-34-1 9-anthrylmethyl phenyl selenide 
• 18255-05-5 benzyl phenyl selenide 
• 4916-40-9 1,2-bis(pyridin-2-yl)ethane 
• 1666-13-3 diphenyl diselenide 

Relevant articles and documents

Metal-free synthesis of unsymmetrical selenides from pyridinium salts and diselenides catalysed by visible light

We report the first metal-free selenolations of pyridinium salts with diselenides to prepare unsymmetrical organoselenides catalysed by visible light. This protocol is an efficient and green method for the preparation of unsymmetrical organoselenides because metal-free conditions and readily accessible diselenides are used.

Transition metal-free coupling reactions of benzylic trimethylammonium salts with di(hetero)aryl disulfides and diselenides

A new protocol was developed to synthesize (enantioenriched) thioethers and selenoethers from (chiral) benzylic trimethylammonium salts and di(hetero)aryl disulfides or diselenides. These syntheses were promoted by the presence of weak base and did not require the use of any transition metal, and resulted in the target products with good to excellent yields (72-94%). Using quaternary ammonium salts synthesized from enantiomerically enriched amines led to highly enantiopure benzylic thioethers and selenoethers (94-99% ee) with configurations reversed from those of their enantioenriched quaternary ammonium salts. This journal is

Metal-free sp3 C-H functionalization: A novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

A DTBP-promoted metal-free and solvent-free formation of C-Se and C-S bonds through sp3 C-H functionalization of methyl arenes with diselenides and disulfides is described. the Partner Organisations 2014.