76371-53-4Relevant academic research and scientific papers
Copper-mediated selective cross-coupling of 1,1-dibromo-1-alkenes and heteronucleophiles: Development of general routes to heterosubstituted alkynes and alkenes
Jouvin, Kevin,Coste, Alexis,Bayle, Alexandre,Legrand, Frederic,Karthikeyan, Ganesan,Tadiparthi, Krishnaji,Evano, Gwilherm
, p. 7933 - 7947 (2013/01/16)
Efficient and general procedures for the cross-coupling of 1,1-dibromoalkenes and N-, O-, and P-nucleophiles are reported. Fine-tuning of the reaction conditions allows for either site-selective, double, or alkynylative cross-coupling, therefore providing
Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: A convenient synthesis of 1-alkenylphosphonates
Evano, Gwilherm,Tadiparthi, Krishnaji,Couty, Francois
supporting information; experimental part, p. 179 - 181 (2011/02/25)
An efficient and stereoselective procedure for the preparation of E-1-alkenylphosphonates by copper-mediated cross-coupling between 1,1-dibromo-1-alkenes and dialkyl phosphites is reported. The reaction allows for formal substitution of both bromine atoms
A new synthesis of π-electron conjugated phosphonates and phosphonic bis(diethylamides) and their SHG activities
Ogawa, Takuji,Usuki, Naoya,Ono, Noboru
, p. 2953 - 2958 (2007/10/03)
A series of vinylic and arylic phosphonates and phosphonic bis(diethylamides) were prepared by copper promoted substitution of the corresponding bromides. These π-electron conjugated phosphonates and phosphonic bis(diethylamides) were investigated to eluc
PALLADIUM-CATALYZED NEW CARBON-PHOSPHORUS BOND FORMATION
Hirao, Toshikazu,Masunaga, Toshio,Yamada, Naoto,Ohshiro, Yoshiki,Agawa, Toshio
, p. 909 - 913 (2007/10/02)
Dialkyl arylphosphonates are prepared by the palladium-catalyzed reaction of aryl bromides with dialkyl phosphite in the presence of triethylamine.The similar treatment of vinyl bromides gives dialkyl vinylphosphonates stereoselectively.
Stereoselective synthesis of vinylphosphonate
Hirao, Toshikazu,Masunaga, Toshio,Ohshiro, Yoshiki,Agawa, Toshio
, p. 3595 - 3598 (2007/10/02)
Dialkyl vinylphosphonate is stereoselectively prepared by palladium-catalyzed reaction of vinyl bromide with dialkyl phosphite.
