76382-79-1

Basic information

• Product Name: 5-methyl-1-phenyl-4-oxahexane
• Synonyms: 5-methyl-1-phenyl-4-oxahexane
• CAS NO: 76382-79-1
• Molecular Weight: 178.274
• Mol File: 76382-79-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-methyl-1-phenyl-4-oxahexane(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methyl-1-phenyl-4-oxahexane(76382-79-1)
• EPA Substance Registry System: 5-methyl-1-phenyl-4-oxahexane(76382-79-1)

Safety Data

• Hazardous Substances Data: 76382-79-1(Hazardous Substances Data)

Upstream product

• 3277-26-7 1,1,3,3-Tetramethyldisiloxane 
• 22767-95-9 1-methylethyl 3-phenylpropionoate 
• 873-49-4 phenylcyclopropane cation radical 
• 67-63-0 isopropyl alcohol 
• 873-49-4 cyclopropylbenzene 
• 623-26-7 terephthalonitrile 

Downstream Products

• 4119-41-9 1-iodo-3-phenylpropan 

Relevant articles and documents

Remarkably high catalyst efficiency of a disilaruthenacyclic complex for hydrosilane reduction of carbonyl compounds

A disilaruthenacyclic complex (1) showed extremely high catalytic activity for hydrosilane reduction of aldehydes and ketones to silyl ethers and secondary and tertiary amides to the corresponding amines. An σ-CAM mechanism was proposed to explain the activity.

PHOTOINDUCED OXIDATIVE CLEAVAGE OF ARYLCYCLOPROPANES IN THE PRESENCE OF ORGANIC ELECTRON-ACCEPTOR

The cyclopropane ring of arylcyclopropanes is oxidatively cleaved by irradiation in polar solvents containing nucleophiles such as alcohols, water, and sodium cyanide in the presence of electron-acceptor such as 1,4-dicyanobenzene and 1-cyanonaphthalene, giving nucleophile-incorporated products.This photoreaction proceeds via an electron-transfer from the cyclopropanes to the excited electron-acceptors, and the cation radicals of arylcyclopropanes are involved as key intermediates.