76465-33-3Relevant academic research and scientific papers
Three-Component Reactions. IX. Methoxychlorination of Butadiene. 1. Composition of Reaction Mixtures Obtained Using Either an Excess of Butadiene or an Excess of Chlorine
Beger, J.,Schiefer, H.,Movsumzade, M.M.,Gurbanov, P.A.
, p. 599 - 609 (2007/10/02)
Methoxychlorination of butadiene with 2 mol chlorine gives saturated secondary addition products 5-15, which were found identical with methoxychlorination products of unsaturated primary addition products 1-4 (investigated by capillar GLC). 1,2 and 3 add chlorine and methanol with high regioselectivity (80-90percent); meso and erythro isomer predominate in MARKOVNIKOV products from 1 and 2 (87percent diastereoselectivity). 5-7 and 11-15 were separated by preparative GLC for structural analysis.
