76475-04-2Relevant articles and documents
Catalytic Electrophilic Alkylation of p-Quinones through a Redox Chain Reaction
Xu, Xiao-Long,Li, Zhi
supporting information, p. 8196 - 8200 (2017/06/30)
Allylation and benzylation of p-quinones was achieved through an unusual redox chain reaction. Mechanistic studies suggest that the existence of trace hydroquinone initiates a redox chain reaction that consists of a Lewis acid catalyzed Friedel–Crafts alkylation and a subsequent redox equilibrium that regenerates hydroquinone. The electrophiles could be various allylic and benzylic esters. The addition of Hantzsch ester as an initiator improves the efficiency of the reaction.
Indium-mediated Reformatsky-Claisen rearrangement
Ishihara, Jun,Watanabe, Yuki,Koyama, Noriko,Nishino, Yukihiro,Takahashi, Keisuke,Hatakeyama, Susumi
experimental part, p. 3659 - 3667 (2011/06/21)
A new variant of the Reformatsky-Claisen rearrangement is described. The reaction of substituted allyl α-bromoacetates with indium and indium(III) chloride under ultrasonication provides a general entry into the functionalized synthon.
Reactions du n=chloroparatoluenesulfonamidate de sodium (chloramine t) sur les olefines en miliu acide organique
Damin, Bernard,Garapon, Jacques,Sillion, Bernard
, p. 1709 - 1710 (2007/10/02)
Vic. chloro-acetoxy and vic. chloro-tosylamino alcanes are the main products of the electrophilic reaction of chloramine T on olefins in acetic acid. The stereochemistry of the acetoxy chloration of the 2-butenes and cyclohexene is trans.