76475-06-4Relevant academic research and scientific papers
Visible-light-triggered Catalytic Halohydrin Synthesis from Epoxides and Trichloroacetonitrile by Copper and Iron Salts
Toda, Yasunori,Tanaka, Katsumi,Matsuda, Riki,Suga, Hiroyuki
, p. 1469 - 1471 (2019)
Preparation of vicinal halohydrins, in which copper or iron chlorides catalyze the ring-opening reaction of epoxides with visible light effectively, is described. The use of trichloroacetonitrile as a halogen source enables catalytic HCl generation under the mild conditions. This method can also be applied to the aziridine ring-opening reaction.
Reactions du n=chloroparatoluenesulfonamidate de sodium (chloramine t) sur les olefines en miliu acide organique
Damin, Bernard,Garapon, Jacques,Sillion, Bernard
, p. 1709 - 1710 (2007/10/02)
Vic. chloro-acetoxy and vic. chloro-tosylamino alcanes are the main products of the electrophilic reaction of chloramine T on olefins in acetic acid. The stereochemistry of the acetoxy chloration of the 2-butenes and cyclohexene is trans.
