7651-91-4Relevant academic research and scientific papers
DISPROPORTIONATION KINETICS OF N-CHLOROMETHYLAMINE AND N-CHLOROETHYLAMINE
Antelo, J. M.,Arce, F.,Parajo, M.,Rodriguez, P.
, p. 1031 - 1036 (2007/10/02)
The kinetics of disproportionation of N-Cl-methylamine and N-Cl-ethylamine in water were studied at acid pH.Its disproportionation and protonation constants and the coefficients of absorption of N,N-dichloramines are calculated and the mechanism of its disproportionation is discussed.
ELECTROCHEMICAL CHLORINATION OF AMINES
Petrosyan, V. A.,Lyalin, B. V.,Smetanin, A. V.
, p. 542 - 546 (2007/10/02)
We have studied the laws governing the electrochemical chlorination of primary and secondary amines in aqueous solution on a ruthenium-titanium anode under conditions of diaphragm electrolysis.It was found that in order to ensure the most complete conversion of the amines into the corresponding chloramines it is necessary to add NaHCO3 to the electrolyte .Under the conditions of electrolysis primary amines are converted almost quantitatively into dichloramines.High yields of the N-chloro-derivatives of secondary amines can be obtained with high current densities and concentrations of NaCl.
Antibacterial agents
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, (2008/06/13)
Novel naphthyridine-, quinoline- and benzoxazine-carboxylic acids as antibacterial agents are described as well as methods for their manufacture, formulation, and use in treating bacterial infections including the description of certain novel intermediates used in the manufacture of the antibacterial agents.
Vacuum Gas/Solid N-Chlorination: Preparative Scale Synthesis of Volatile N-Chloramines
Guillemin, J. C.,Denis, J. M.
, p. 1131 - 1133 (2007/10/02)
A simple method for the preparative scale synthesis of volatile chloramines free from impurities starting from the corresponding primary or secondary amine using N-chlorosuccinimide as chlorinating agent is described.
