76524-56-6

Basic information

• Product Name: Benzene, (4-methyl-1,5-hexadienyl)-, (E)-
• CAS NO: 76524-56-6
• Molecular Formula: C13H16
• Molecular Weight: 172.27
• Mol File: 76524-56-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, (4-methyl-1,5-hexadienyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (4-methyl-1,5-hexadienyl)-, (E)-(76524-56-6)
• EPA Substance Registry System: Benzene, (4-methyl-1,5-hexadienyl)-, (E)-(76524-56-6)

Safety Data

• Hazardous Substances Data: 76524-56-6(Hazardous Substances Data)

Upstream product

• 563-52-0 2-chloro-3-butene 
• 54962-99-1 cinnamyllithium 
• 21040-45-9 Cinnamyl acetate 
• 35998-93-7 tri-n-butylcrotyltin 
• 100-42-5 styrene 
• 78-79-5 isoprene 
• 4392-24-9 Cinnamyl bromide 
• 18292-28-9 1-(trimethylsilyl)but-2-ene 
• 40595-34-4 (E)-trimethyl(3-phenylallyl)silane 
• 934-10-1 3-phenylbut-1-ene 
• 111195-58-5 but-2-enylzinc bromide 
• 114067-35-5 ((E)-2-butenyl)trifluorosilane 
• 21087-29-6 trans-3-phenylprop-2-enyl chloride 
• 16327-44-9 Crotyllithium 

Relevant articles and documents

Diene compound and process for producing the same

The invention provides a chain diene compound with desirable regioselectivity, in the presence of a specific ruthenium compound. This chain diene compound is a promising raw material for terpene. It has a structure represented by the general formula (IX): wherein R1represents H, a C1-C6alkyl group which may be substituted or a C2-C6alkenyl group which may be substituted, R2represents a phenyl group which may have a C1-C4alkyl group or a C1-C12acyloxy group which may have a phenyl group or a naphthyl group, or a benzyl group or R2is a hydroxy group which reversibly forms an aldehyde group through shifting of the position of the double bond adjacent to said hydroxy group. The chain diene compound is produced by reacting 2-substituted-1,3-butadienes with terminal olefins in the presence of a ruthenium compound in a hydrophilic solvent. Further, the above method provides an inexpensive process for preparing a mild fragrant component and a perfume composition, such as 4-methyl-5-hexen-1-al and 4-vinyl-8-methyl-7-nonenal.

Oxovanadium-induced oxidative desilylation of allylic and benzylic silanes

Cinnamyltrimethylsilane underwent desilylation via one-electron oxidation with VO(OEt)Cl2, which was applied to the cross-coupling with the less oxidizable allylic silanes to give the corresponding 1,5-hexadienes. Chlorination or aromatization

γ-Selective Cross-Coupling Reactions of Allyltrifluorosilanes: A New Approach to Regiochemical Control in Allylic Systems

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