76587-07-0Relevant academic research and scientific papers
Stereoselective synthesis of allyl ethers using α,β-unsaturated acylsilanes
Honda, Mitsunori,Takatera, Takehide,Ui, Ryosuke,Kunimoto, Ko-Ki,Segi, Masahito
, p. 864 - 869 (2017)
The reaction behavior of silylvinylmethanols with acid catalysts was investigated. The starting silylvinylmethanols 2 were prepared by the reaction of the corresponding α,β-unsaturated acylsilanes 1 with organocerium reagents. The reaction of 2 with TsOH
Lithium keten thioacetalides. Factors influencing α- versus γ-alkylation
Murphy, William S.,Wattanasin, Sompong
, p. 2678 - 2682 (2007/10/02)
Alkylation of the lithium salt of the vinyl-1,3-dithian (2; R = CH 3) occurred exclusively at the α-carbon. However both α- and γ-alkylation was observed with the substrate (2; R = C 6H5). A systematic investigation reveal
