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7659-86-1

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7659-86-1 Usage

Uses

Different sources of media describe the Uses of 7659-86-1 differently. You can refer to the following data:
1. 2-Ethylhexyl mercaptoacetate can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
2. Thioglycolic Acid 2-Ethylhexyl Ester is a chain transfer agent that is useful for preparing latex with flame retardancy.

Synthesis

52.1 g (0.2 mol) of N,N'-diphenyl-1,4-phenylenediamine and 81.7 g (0.4 mol) of 2-ethylhexyl thioglycollate in 200 ml of ethanol are initially placed in a 750 ml sulfonation flask equipped with a propeller stirrer, and are heated to reflux temperature. 36.7 g (0.44 mol) of 36% aqueous formaldehyde are added dropwise in the course of 2 hours, and the reaction mixture is then boiled under reflux for 16 hours. The batch is concentrated on a rotary evaporator, and the residue is then dried at 80° C. for 2 hours under a high vacuum. 127.3 g (91.8% of theory) of a dark brown oil are obtained. Analysis: Calculated; C 69.33%, H 8.15%, N 4.04%, S 9.25%, Found; C 70.2%, H 8.13%, N 3.96%, S 9.29%.

Check Digit Verification of cas no

The CAS Registry Mumber 7659-86-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,5 and 9 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 7659-86:
(6*7)+(5*6)+(4*5)+(3*9)+(2*8)+(1*6)=141
141 % 10 = 1
So 7659-86-1 is a valid CAS Registry Number.
InChI:InChI=1/C10H20O2S/c1-3-5-6-9(4-2)7-13-8-10(11)12/h9H,3-8H2,1-2H3,(H,11,12)/p-1

7659-86-1 Well-known Company Product Price

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  • Aldrich

  • (88670)  2-Ethylhexylthioglycolate  ≥95.0% (GC)

  • 7659-86-1

  • 88670-500ML

  • 795.60CNY

  • Detail

7659-86-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name Thioglycolic Acid 2-Ethylhexyl Ester

1.2 Other means of identification

Product number -
Other names Acetic acid, mercapto-, 2-ethylhexyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Intermediates,Processing aids, not otherwise listed
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7659-86-1 SDS

7659-86-1Synthetic route

10H-phenothiazine
92-84-2

10H-phenothiazine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

N-(2-Ethylhexyloxycarbonylmethylthiomethyl)-phenothiazine

N-(2-Ethylhexyloxycarbonylmethylthiomethyl)-phenothiazine

Conditions
ConditionsYield
With paraformaldehyde99%
10H-phenothiazine
92-84-2

10H-phenothiazine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

N-(2-Ethylhexyloxycarbonylmethylthiomethyl)-phenothiazine

N-(2-Ethylhexyloxycarbonylmethylthiomethyl)-phenothiazine

Conditions
ConditionsYield
With paraformaldehyde99%
n-octyltin trichloride
3091-25-6

n-octyltin trichloride

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

octyltin tris(isooctyl thioglycollate)
27107-89-7

octyltin tris(isooctyl thioglycollate)

Conditions
ConditionsYield
With sodium hydroxide In water at 50℃; for 2h; Product distribution / selectivity;98%
n-octyltin trichloride
3091-25-6

n-octyltin trichloride

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

octyltin tris(isooctyl thioglycollate)
27107-89-7

octyltin tris(isooctyl thioglycollate)

Conditions
ConditionsYield
With sodium hydroxide In water at 50℃; for 2h; Product distribution / selectivity;98%
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-Ethylhexyl N,N-diphenylaminomethylthioacetate

2-Ethylhexyl N,N-diphenylaminomethylthioacetate

Conditions
ConditionsYield
With diphenylamine; paraformaldehyde In water; toluene97.6%
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-Ethylhexyl N,N-diphenylaminomethylthioacetate

2-Ethylhexyl N,N-diphenylaminomethylthioacetate

Conditions
ConditionsYield
With diphenylamine; paraformaldehyde In water; toluene97.6%
N-phenyl-1-naphthylamine
90-30-2

N-phenyl-1-naphthylamine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-Ethylhexyl N-phenyl-N-naphthylaminomethylthioacetate

2-Ethylhexyl N-phenyl-N-naphthylaminomethylthioacetate

Conditions
ConditionsYield
With paraformaldehyde96.8%
N-phenyl-1-naphthylamine
90-30-2

N-phenyl-1-naphthylamine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-Ethylhexyl N-phenyl-N-naphthylaminomethylthioacetate

2-Ethylhexyl N-phenyl-N-naphthylaminomethylthioacetate

Conditions
ConditionsYield
With paraformaldehyde96.8%
3-Bromopyridine
626-55-1

3-Bromopyridine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

C15H23NO2S

C15H23NO2S

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 2h;96.26%
3-Bromopyridine
626-55-1

3-Bromopyridine

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

C15H23NO2S

C15H23NO2S

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In 1,4-dioxane at 100℃; for 2h;96.26%
methanol
67-56-1

methanol

bis(2-methoxycarbonylethyl)tin dichloride
10175-01-6

bis(2-methoxycarbonylethyl)tin dichloride

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

di(2-methoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
66491-79-0

di(2-methoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In methanol byproducts: NaCl; addn. of alcohol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;95%
methanol
67-56-1

methanol

bis(2-methoxycarbonylethyl)tin dichloride
10175-01-6

bis(2-methoxycarbonylethyl)tin dichloride

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

di(2-methoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
66491-79-0

di(2-methoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In methanol byproducts: NaCl; addn. of alcohol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;95%
formaldehyd
50-00-0

formaldehyd

2,6-di-tert-butylphenol
128-39-2

2,6-di-tert-butylphenol

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 2-(3,5-di-tert-butyl-4-hydroxybenzylthio)acetate

2-ethylhexyl 2-(3,5-di-tert-butyl-4-hydroxybenzylthio)acetate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-(dimethylaminomethyl)phenol In N,N-dimethyl-formamide at 120℃; for 4h;92%
formaldehyd
50-00-0

formaldehyd

2,6-di-tert-butylphenol
128-39-2

2,6-di-tert-butylphenol

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 2-(3,5-di-tert-butyl-4-hydroxybenzylthio)acetate

2-ethylhexyl 2-(3,5-di-tert-butyl-4-hydroxybenzylthio)acetate

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-(dimethylaminomethyl)phenol In N,N-dimethyl-formamide at 120℃; for 4h;92%
ethanol
64-17-5

ethanol

Cl2Sn(CH2CH2COOC2H5)2
10175-02-7

Cl2Sn(CH2CH2COOC2H5)2

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

di(2-ethoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
86176-72-9

di(2-ethoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol byproducts: NaCl; addn. of alcohol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;92%
ethanol
64-17-5

ethanol

Cl2Sn(CH2CH2COOC2H5)2
10175-02-7

Cl2Sn(CH2CH2COOC2H5)2

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

di(2-ethoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
86176-72-9

di(2-ethoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethanol byproducts: NaCl; addn. of alcohol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;92%
(C6H5CH2OC(O)CH2CH2)2SnCl2
88261-93-2

(C6H5CH2OC(O)CH2CH2)2SnCl2

benzyl alcohol
100-51-6

benzyl alcohol

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

(C6H5CH2OC(O)CH2CH2)2Sn(SCH2CO2CH2CH(C2H5)(CH2)3CH3)2
88261-95-4

(C6H5CH2OC(O)CH2CH2)2Sn(SCH2CO2CH2CH(C2H5)(CH2)3CH3)2

Conditions
ConditionsYield
With sodium hydrogencarbonate In further solvent(s) byproducts: NaCl; addn. of PhCH2OH to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;90%
(C6H5CH2OC(O)CH2CH2)2SnCl2
88261-93-2

(C6H5CH2OC(O)CH2CH2)2SnCl2

benzyl alcohol
100-51-6

benzyl alcohol

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

(C6H5CH2OC(O)CH2CH2)2Sn(SCH2CO2CH2CH(C2H5)(CH2)3CH3)2
88261-95-4

(C6H5CH2OC(O)CH2CH2)2Sn(SCH2CO2CH2CH(C2H5)(CH2)3CH3)2

Conditions
ConditionsYield
With sodium hydrogencarbonate In further solvent(s) byproducts: NaCl; addn. of PhCH2OH to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;90%
Cl2Sn(CH2CH2COOCH2CH2CH2CH3)2
61470-33-5

Cl2Sn(CH2CH2COOCH2CH2CH2CH3)2

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

butan-1-ol
71-36-3

butan-1-ol

di(2-butoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
84332-98-9

di(2-butoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In further solvent(s) byproducts: NaCl; addn. of n-butanol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;90%
Cl2Sn(CH2CH2COOCH2CH2CH2CH3)2
61470-33-5

Cl2Sn(CH2CH2COOCH2CH2CH2CH3)2

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

butan-1-ol
71-36-3

butan-1-ol

di(2-butoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)
84332-98-9

di(2-butoxycarbonylethyl)tin S,S'-bis-(2-ethylhexyl thioglycolate)

Conditions
ConditionsYield
With sodium hydrogencarbonate In further solvent(s) byproducts: NaCl; addn. of n-butanol to mixt. of Sn compd. and HSCH2COOC8H17-i, 50-60°C, slow addn. of NaHCO3, 2-3h, NaCl removed by washing with water; mass spectroscopy;90%
di(2-ethylhexyl) 3,7-bis(trifluoromethanesulfonyloxy)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

di(2-ethylhexyl) 3,7-bis(trifluoromethanesulfonyloxy)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

bis(2-ethylhexyl) 3,7-bis((2-((2-ethylhexyl)oxy)-2-oxoethyl)thio)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

bis(2-ethylhexyl) 3,7-bis((2-((2-ethylhexyl)oxy)-2-oxoethyl)thio)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere;70%
di(2-ethylhexyl) 3,7-bis(trifluoromethanesulfonyloxy)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

di(2-ethylhexyl) 3,7-bis(trifluoromethanesulfonyloxy)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

bis(2-ethylhexyl) 3,7-bis((2-((2-ethylhexyl)oxy)-2-oxoethyl)thio)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

bis(2-ethylhexyl) 3,7-bis((2-((2-ethylhexyl)oxy)-2-oxoethyl)thio)benzo[1,2-b:4,5-b']dithiophene-2,6-dicarboxylate

Conditions
ConditionsYield
With potassium phosphate In N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere;70%
2-ethylhexyl vinyl ether
103-44-6

2-ethylhexyl vinyl ether

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 2-(2-(2-ethylhexyloxy)ethylthio)acetate

2-ethylhexyl 2-(2-(2-ethylhexyloxy)ethylthio)acetate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 115℃; for 24h; Sealed tube;68%
2-ethylhexyl vinyl ether
103-44-6

2-ethylhexyl vinyl ether

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 2-(2-(2-ethylhexyloxy)ethylthio)acetate

2-ethylhexyl 2-(2-(2-ethylhexyloxy)ethylthio)acetate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) at 115℃; for 24h; Sealed tube;68%
(+/-)-(E)-1-((1RS,2SR)-2,6,6-trimethylcyclohex-3-enyl)but-2-en-1-one

(+/-)-(E)-1-((1RS,2SR)-2,6,6-trimethylcyclohex-3-enyl)but-2-en-1-one

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl (±)-({4-oxo-4-[(1RS,2SR)-2,6,6-trimethylcyclohex-3-en-1-yl]butan-2-yl}sulfanyl)acetate

2-ethylhexyl (±)-({4-oxo-4-[(1RS,2SR)-2,6,6-trimethylcyclohex-3-en-1-yl]butan-2-yl}sulfanyl)acetate

Conditions
ConditionsYield
In dimethyl sulfoxide at 20℃; for 72h; Michael Addition;62%
(+/-)-(E)-1-((1RS,2SR)-2,6,6-trimethylcyclohex-3-enyl)but-2-en-1-one

(+/-)-(E)-1-((1RS,2SR)-2,6,6-trimethylcyclohex-3-enyl)but-2-en-1-one

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl (±)-({4-oxo-4-[(1RS,2SR)-2,6,6-trimethylcyclohex-3-en-1-yl]butan-2-yl}sulfanyl)acetate

2-ethylhexyl (±)-({4-oxo-4-[(1RS,2SR)-2,6,6-trimethylcyclohex-3-en-1-yl]butan-2-yl}sulfanyl)acetate

Conditions
ConditionsYield
In dimethyl sulfoxide at 20℃; for 72h; Michael Addition;62%
3-aminoindazole
874-05-5

3-aminoindazole

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 3-aminobenzo[b]thiophene-2-carboxylate

2-ethylhexyl 3-aminobenzo[b]thiophene-2-carboxylate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper diacetate; sodium hydroxide In water; acetonitrile at 80℃; for 22h; Sealed tube; Inert atmosphere;62%
3-aminoindazole
874-05-5

3-aminoindazole

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 3-aminobenzo[b]thiophene-2-carboxylate

2-ethylhexyl 3-aminobenzo[b]thiophene-2-carboxylate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; copper diacetate; sodium hydroxide In water; acetonitrile at 80℃; for 22h; Sealed tube; Inert atmosphere;62%
4-bromothiophene-3-carboxaldehyde
18791-78-1

4-bromothiophene-3-carboxaldehyde

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl thieno[3,4-b]thiophene-2-carboxylate

2-ethylhexyl thieno[3,4-b]thiophene-2-carboxylate

Conditions
ConditionsYield
With copper(II) oxide; potassium carbonate In dimethyl sulfoxide at 60℃; for 16h; Inert atmosphere;56%
With potassium carbonate; copper(II) oxide In N,N-dimethyl-formamide
4-bromothiophene-3-carboxaldehyde
18791-78-1

4-bromothiophene-3-carboxaldehyde

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl thieno[3,4-b]thiophene-2-carboxylate

2-ethylhexyl thieno[3,4-b]thiophene-2-carboxylate

Conditions
ConditionsYield
With copper(II) oxide; potassium carbonate In dimethyl sulfoxide at 60℃; for 16h; Inert atmosphere;56%
With potassium carbonate; copper(II) oxide In N,N-dimethyl-formamide
4-chloro-3-(methoxalyl)coumarin
1338214-56-4

4-chloro-3-(methoxalyl)coumarin

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-(2-ethylhexyl) 3-methyl 4-oxo-4H-thieno[3,2-c]chromene-2,3-dicarboxylate
1338214-87-1

2-(2-ethylhexyl) 3-methyl 4-oxo-4H-thieno[3,2-c]chromene-2,3-dicarboxylate

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0 - 20℃; Inert atmosphere; regioselective reaction;54%
4-chloro-3-(trifluoroacetyl)-2H-1-benzopyran-2-one
1264667-66-4

4-chloro-3-(trifluoroacetyl)-2H-1-benzopyran-2-one

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 4-oxo-3-(trifluoromethyl)-4H-thieno[3,2-c]chromene-2-carboxylate
1338214-86-0

2-ethylhexyl 4-oxo-3-(trifluoromethyl)-4H-thieno[3,2-c]chromene-2-carboxylate

Conditions
ConditionsYield
Stage #1: 4-chloro-3-(trifluoroacetyl)-2H-1-benzopyran-2-one; mercaptoacetic acid 2-ethylhexyl ester With triethylamine In N,N-dimethyl-formamide at 20℃; for 16h; Inert atmosphere;
Stage #2: With chloro-trimethyl-silane In N,N-dimethyl-formamide at 100℃; for 6h; Inert atmosphere; regioselective reaction;
47%
2,3‐dichloro-5,6‐dimethyl‐1,4‐benzoquinone
15707-31-0

2,3‐dichloro-5,6‐dimethyl‐1,4‐benzoquinone

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

A

2-ethylhexyl 2-(2-chloro-4,5-dimethyl-3,6-dioxocyclohexa-1,4-dienylthio)acetate

2-ethylhexyl 2-(2-chloro-4,5-dimethyl-3,6-dioxocyclohexa-1,4-dienylthio)acetate

B

bis(2-ethylhexyl)2,2’-(4,5-dimethyl-3,6-dioxocyclohexa-1,4-diene-1,2-diyl) bis(sulfanediyl) diacetate

bis(2-ethylhexyl)2,2’-(4,5-dimethyl-3,6-dioxocyclohexa-1,4-diene-1,2-diyl) bis(sulfanediyl) diacetate

Conditions
ConditionsYield
In ethanol at 20℃;A 38%
B 8%
6-bromo-2-isooctyl-2H-benzo[d][1,2,3]triazole-5-carbaldehyde

6-bromo-2-isooctyl-2H-benzo[d][1,2,3]triazole-5-carbaldehyde

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-(2-ethylhexyl)-2H-benzo[d][1,2,3]triazolo[2,3-f]thiophene-6-carboxylic acid 2-ethylhexyl ester

2-(2-ethylhexyl)-2H-benzo[d][1,2,3]triazolo[2,3-f]thiophene-6-carboxylic acid 2-ethylhexyl ester

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 80℃; for 2h; Microwave irradiation;36.2%
dibutyl 2,5-dibromoterephthalate
58613-36-8

dibutyl 2,5-dibromoterephthalate

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

methyl iodide
74-88-4

methyl iodide

C14H10O6S2

C14H10O6S2

Conditions
ConditionsYield
Stage #1: dibutyl 2,5-dibromoterephthalate; mercaptoacetic acid 2-ethylhexyl ester With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine at 100℃; for 15h;
Stage #2: With potassium tert-butylate In N,N-dimethyl-formamide at 100℃; for 3h;
Stage #3: methyl iodide Further stages;
31%
C16H20Br2O4

C16H20Br2O4

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

methyl iodide
74-88-4

methyl iodide

C14H10O6S2

C14H10O6S2

Conditions
ConditionsYield
Stage #1: C16H20Br2O4; mercaptoacetic acid 2-ethylhexyl ester With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine at 100℃; for 15h;
Stage #2: With potassium tert-butylate In N,N-dimethyl-formamide at 100℃; for 3h;
Stage #3: methyl iodide Further stages;
21%
(E)-2-octen-4-one
22286-99-3

(E)-2-octen-4-one

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

(±)-2-ethylhexyl 2-((4-oxooctan-2-yl)thio)acetate

(±)-2-ethylhexyl 2-((4-oxooctan-2-yl)thio)acetate

Conditions
ConditionsYield
at 20℃; for 576h;7%
2-acetyl-1,4-naphthoquinone
5813-57-0

2-acetyl-1,4-naphthoquinone

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

(3-acetyl-1,4-dihydroxy-naphthalen-2-ylsulfanyl)-acetic acid 2-ethyl-hexyl ester

(3-acetyl-1,4-dihydroxy-naphthalen-2-ylsulfanyl)-acetic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.25h;
2-Acetyl-1,4-benzoquinone
1125-55-9

2-Acetyl-1,4-benzoquinone

mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

(2-acetyl-3,6-dihydroxy-phenylsulfanyl)-acetic acid 2-ethyl-hexyl ester

(2-acetyl-3,6-dihydroxy-phenylsulfanyl)-acetic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.25h;
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 3-methyl-4,7-dioxo-4,7-dihydrobenzo[b]thiophene-2-carboxylate

2-ethylhexyl 3-methyl-4,7-dioxo-4,7-dihydrobenzo[b]thiophene-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
3: aq. HCl / acetonitrile / 0.08 h
4: CAN / acetonitrile; H2O / 0.5 h
View Scheme
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

4,7-dihydroxy-3-methyl-benzo[b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

4,7-dihydroxy-3-methyl-benzo[b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
3: aq. HCl / acetonitrile / 0.08 h
View Scheme
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

2-ethylhexyl 3-methyl-4,9-dioxo-4,9-dihydronaphtho[2,3-b]thiophene-2-carboxylate

2-ethylhexyl 3-methyl-4,9-dioxo-4,9-dihydronaphtho[2,3-b]thiophene-2-carboxylate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
3: aq. HCl / diethyl ether
4: air; silica gel / hexane; ethyl acetate
View Scheme
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

4,9-dihydroxy-3-methyl-naphtho[2,3-b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

4,9-dihydroxy-3-methyl-naphtho[2,3-b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
3: aq. HCl / diethyl ether
View Scheme
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

3-methyl-4,7-bis-trimethylsilanyloxy-benzo[b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

3-methyl-4,7-bis-trimethylsilanyloxy-benzo[b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
View Scheme
mercaptoacetic acid 2-ethylhexyl ester
7659-86-1

mercaptoacetic acid 2-ethylhexyl ester

3-methyl-4,9-bis-trimethylsilanyloxy-naphtho[2,3-b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

3-methyl-4,9-bis-trimethylsilanyloxy-naphtho[2,3-b]thiophene-2-carboxylic acid 2-ethyl-hexyl ester

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrahydrofuran / 0.25 h / 20 °C
2: 3 h / 80 °C
View Scheme

7659-86-1Upstream product

7659-86-1Relevant articles and documents

Sulfur-containing compounds as antioxidants for lubricants and elastomers

-

, (2008/06/13)

Compounds of the formula (I) STR1 in which the Rs independently of one another are H, phenyl, naphthyl or C7 -C30 alkaryl and R1 is H, C1 -C8 alkyl, C7 -C9 aralkyl, C5 -C12 cycloalkyl, phenyl, naphthyl, C7 -C30 alkaryl or a group of the formula (II) R2 is C7 -C30 alkaryl, phenyl, naphthyl or phenyl containing, in the para-position, an HO or C1 -C18 alkoxy group or a group of the formulae STR2 or R1 and R2, together with the nitrogen atom to which they are attached, are a radical of the formula (III) STR3 R3 is a radical of the formulae --(CH2)b --COOR6 or --(CH2)2 OCOR7, a is the number 1, 2 or 3 and b is the number 1 or 2, and R4 is phenyl or a group of the formula (II), the two R5 s independently of one another are H, C1 -C24 alkyl, C5 -C12 cycloalkyl or C7 -C9 aralkyl, and R6 is H, C1 -C18 alkyl or benzyl, R7 is C1 -C14 alkyl, phenyl or a group of the formula in which Y is --O-- or --S--, a is the number 1, 2 or 3 and m is the number 1 or 2, B is a direct bond, --S--, --S--S-- or a C1 -C12 alkylene radical, X in the formula (III) is a direct bond, --S-- or a group of the formulae STR4 form a phenothiazine, phenazine, acridine or carbazole radical.

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