765941-34-2

Upstream product

• 765941-29-5 (2S,3R,4R,5S,6S)-3,7-bis(tert-butyldimethylsilyloxy)-2,4,6-trimethylheptane-1,5-diol 
• 122-04-3 4-nitro-benzoyl chloride 
• 112057-64-4 (R)-3-(tert-butyldimethylsilyloxy)-2-methylpropan-1-ol 
• 104701-87-3 (2S)-3-(tert-butyl-dimethyl-silyloxy)-2-methyl-propanal 
• 93454-85-4 (S)-3-(tert-butyldimethylsilyloxy)-2-methylpropionic acid methyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 106296-58-6 (2S,3R,4S)-1-(tert-butyldimethylsilyloxy)-2,4-dimethylhex-5-en-3-ol 
• 765941-27-3 (3R,4S,5R,6S)-6-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-4-tert-butyldimethylsilyloxy-3,5-dimethyltetrahydropyran-2-one 
• 765941-23-9 (3S,4S,5S,6S)-6-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-3,4-dihydroxy-5-methyltetrahydropyran-2-one 
• 765942-02-7 (3R,4S,5S,6S)-6-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-4-hydroxy-3,5-dimethyltetrahydropyran-2-one 
• 765942-01-6 (1R,2S)-1-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-2-methyl-3-butenyl prop-2-enoate 
• 765941-25-1 (4S,5S,6S)-6-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-4-hydroxy-5-methyltetrahydropyran-2-one 
• 765941-21-7 (5S,6R)-6-((1S)-2-tert-butyldimethylsilyloxy-1-methylethyl)-5-methyl-5,6-dihydropyran-2-one 

Downstream Products

• 765942-03-8 (2S,3R,4R,5S,6S)-3,7-bis(tert-butyldimethylsilyloxy)-5-triethylsilyloxy-2,4,6-trimethylheptyl p-nitrobenzoate 

Relevant academic research and scientific papers

Diastereoselective dihydroxylation and regioselective deoxygenation of dihydropyranones: A novel protocol for the stereoselective synthesis of C 1-C8 and C15-C21 subunits of (+)-discodermolide

Diastereoselective dihydroxylation of dihydropyranones and subsequent regioselective α-deoxygenation provides 1,3-trans-β-hydroxy-6- lactones stereoselectively. This protocol has been applied for the synthesis of C1-C8 and C15-C21 subunits of (+)-discodermolide.