82201-24-9

Basic information

• Product Name: (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane
• Synonyms: (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane
• CAS NO: 82201-24-9
• Molecular Weight: 280.349
• Mol File: 82201-24-9.mol

Chemical Properties

• CAS DataBase Reference: (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane(CAS DataBase Reference)
• NIST Chemistry Reference: (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane(82201-24-9)
• EPA Substance Registry System: (6-Methyl-cyclohex-1-enyl)-diphenyl-phosphane(82201-24-9)

Safety Data

• Hazardous Substances Data: 82201-24-9(Hazardous Substances Data)

Upstream product

• 583-60-8 2-Methylcyclohexanone 
• 76605-82-8 6-methyl-cyclohex-1-en-1-yl trifluoromethanesulfonate 
• 829-85-6 diphenylphosphane 
• 63883-66-9 2-methylcyclohexanone (2,4,6-triisopropylbenzenesulfonyl)hydrazone 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 82201-18-1 C₁₉H₂₁OP 

Relevant articles and documents

Palladium-catalyzed synthesis of vinyl phosphines from ketones

The palladium-catalyzed conversion of vinyl triflates to vinyl phosphines is reported. This process allows for the synthesis of vinyl phosphines from ketones. Selective enolization of a variety of ketones followed by trapping of the enolate as the vinyl triflate is reported. The vinyl triflates are then converted to the corresponding vinyl phosphine through palladium catalysis. The resulting vinyl phosphines can then be reduced to give alkyl phosphines.

ENEPHOSPHINILATION

A general method is described for the formation of vinylphosphines from arylsulfonylhydrazones.Oxidation of the resulting vinylphosphines yields phosphine oxides.