76625-78-0

Basic information

• Product Name: 1-phenylvinyl phosphate
• Synonyms: 1-phenylvinyl phosphate
• CAS NO: 76625-78-0
• Molecular Formula: C8H9 O4 P . 2 Na
• Molecular Weight: 0
• Mol File: 76625-78-0.mol

Chemical Properties

• Boiling Point: 394.2°C at 760 mmHg
• Flash Point: 192.2°C
• Appearance: /
• Vapor Pressure: 6.4E-07mmHg at 25°C
• CAS DataBase Reference: 1-phenylvinyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylvinyl phosphate(76625-78-0)
• EPA Substance Registry System: 1-phenylvinyl phosphate(76625-78-0)

Safety Data

• Hazardous Substances Data: 76625-78-0(Hazardous Substances Data)

Usage

General Description

1-phenylvinyl phosphate, also known as phenyl vinyl phosphate, is an organophosphate compound with the chemical formula C8H9O4P. It is a colorless liquid with a fruity odor, commonly used as a flame retardant additive in the production of plastics, coatings, and textiles. It acts as a chemical intermediate in the synthesis of other phosphorus-containing compounds and is also used as a flame retardant in the manufacturing of acrylics, polyurethanes, and epoxy resins. However, 1-phenylvinyl phosphate is a potential irritant to the skin, eyes, and respiratory system and may have harmful effects on aquatic organisms, and its use and disposal must be carefully managed to minimize environmental impact.

InChI:InChI=1/C8H9O4P/c1-7(12-13(9,10)11)8-5-3-2-4-6-8/h2-6H,1H2,(H2,9,10,11)/p-2

Upstream product

• 84959-95-5 (2-bromo-1,3-diphenyl-3-oxo-1-propyl)phosphonic acid 
• 98-86-2 acetophenone 
• 70334-78-0 monoanilinium 1-phenylethenyl hydrogen phosphate 

Relevant articles and documents

Enol Phosphates from the Action of Monomeric Metaphosphate Ion on Ketones

Prior research from this laboratory had demonstrated that monomeric metaphosphate ion, generated by fragmentation from β-bromophosphonate dianions, reacts with acetophenone in the presence of excess base to give a modest yield of 1-phenylvinyl phosphate.This paper expands on that finding; it presents studies of the effects of concentration of reagents, of solvents, and of variation in amine structure (i.e., of the base) on the reaction.These studies lead to experimental conditions where the yield of the enol phosphate of acetophenone, based on the β-bromophosphonic acid used, exceeds 80percent.Several other ketones can be similarly converted to their enol phosphates, although in inferior yield.

Monomeric Metaphosphate Anion: Reaction with Carbonyl Groups

The elusive monomeric metaphosphate anion is generated rapidly at room temperature by the fragmentation of threo- or erythro- (1,2-dibromo-1-phenylpropyl)phosphonate in the presence of a hindered base; it reacts at the carbonyl groups of acetophenone and