7671-12-7Relevant academic research and scientific papers
Competition of methanol and tert-butanol in nucleophilic substitution at phosphorus atom
Cieplucha, Agnieszka,Jankowski, Stefan
experimental part, p. 1448 - 1453 (2010/03/24)
2,3-Oxaphosphabicyclo[2.2.2]octene 1 reacts with alcohols simultaneously according to two competitive mechanisms: bimolecular addition-elimination and unimolecular elimination-addition with the intermediacy of metaphosphonate Ph-PO2 (2). In 1,2-dichloroet
Regioselective formation of a 2,3-oxaphosphabicyclo[2.2.2] octene 3-oxide in baeyer-villiger type oxidation; a dual pathway for its fragmentation
Jankowski, Stefan,Kovacs, Janos,Huben, Krzysztof,Blaszczyk, Michal,Glowka, Marek,Keglevich, Gyoergy
, p. 369 - 375 (2007/10/03)
The O-insertion reaction of a 7-phosphanorbornene (3) unsubstituted on the double-bond gave the corresponding 2,3-oxaphosphabicyclo-[2.2.2]octene oxide (4a) in a regioselective manner that was useful in the fragmentation-related phosphonylation of alcohol
