767340-72-7

Upstream product

• 651718-17-1 2-O-acetyl-3,4,6-tri-O-benzyl-D-mannono-1,5-lactone 
• 1730-25-2 allylmagnesium bromide 
• 29073-91-4 1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 
• 68681-00-5 3,4,6-tri-O-benzyl-1,2-O-<1-(R)-methoxyethylidene>-β-D-mannopyranose 
• 3254-16-8 3,4,6-tri-O-acetyl-1,2-O-(1-methoxyethylidene)-β-D-mannopyranose 

Downstream Products

• 192929-33-2 1-(3',4',6'-tri-O-benzyl-β-D-mannopyranosyl)prop-2-ene 
• 767340-73-8 1-(2'-O-acetyl-3',4',6'-tri-O-benzyl-β-D-mannopyranosyl)prop-2-ene 

Relevant academic research and scientific papers

Stereoselective synthesis of allyl-C-mannosyl compounds: Use of a temporary silicon connection in intramolecular allylation strategies with allylsilanes

Methyl mannoside 16 containing an allyldimethylsilyl ether at C(2) was synthesized in nine steps from D-mannose. Reaction with TMSOTf in MeCN at room-temperature effected C-glycosylation to provide the α-allyl-C- mannosyl product 18 with excellent stereos