651718-17-1Relevant articles and documents
Expedient and versatile formation of novel amino-deoxy-ketoheptuloses
Leshch, Yevgeniy,Jacobsen, Anna,Thimm, Julian,Thiem, Joachim
supporting information, p. 4948 - 4951 (2013/10/22)
Novel monoketoheptuloses have been synthesized employing an amination step in a pre- and/or post-C1 chain elongation using a Petasis reagent by starting from aldohexoses or aldohexosamines. A series of gluco and manno configured 1-/3-deoxy-1-/3-amino-keto
Stereoselective synthesis of allyl-C-mannosyl compounds: Use of a temporary silicon connection in intramolecular allylation strategies with allylsilanes
Beignet, Julien,Tiernan, James,Woo, Chang H.,Kariuki, Benson M.,Cox, Liam R.
, p. 6341 - 6356 (2007/10/03)
Methyl mannoside 16 containing an allyldimethylsilyl ether at C(2) was synthesized in nine steps from D-mannose. Reaction with TMSOTf in MeCN at room-temperature effected C-glycosylation to provide the α-allyl-C- mannosyl product 18 with excellent stereos
Synthesis of monosaccharide-derived spirocyclic cyclopropylamines and their evaluation as glycosidase inhibitors
Bluechel, Christian,Ramana, Chepuri Venkata,Vasella, Andrea
, p. 2998 - 3036 (2007/10/03)
The glucose-, mannose-, and galactose-derived spirocyclic cyclopropylammonium chlorides 1a - 1d, 2a - 2d and 3a-3d were prepared as potential glycosidase inhibitors. Cyclopropanation of the diazirine 5 with ethyl acrylate led in 71% yield to a 4:5:1:20 mi