76833-14-2Relevant academic research and scientific papers
New, general, and practical enamine cyclopropanation using dichloromethane
Tsai, Chia-Chung,Hsieh, I.-Lin,Cheng, Tsung-Ting,Tsai, Ping-Kuei,Lin, Kuo-Wei,Yan, Tu-Hsin
, p. 2261 - 2263 (2006)
Dichloromethane serves as a novel electrophilic carbene equivalent which adds to an enamine double bond. The presence of other alkene moieties in the enamine partner is well tolerated. Even enamines derived from sterically hindered ketones react readily with dichloromethane promoted by TiCl 4-Mg.
