76886-35-6Relevant articles and documents
Alkyl Ethers as Traceless Hydride Donors in Br?nsted Acid Catalyzed Intramolecular Hydrogen Atom Transfer
Gandamana, Dhika Aditya,Wang, Bin,Tejo, Ciputra,Bolte, Benoit,Gagosz, Fabien,Chiba, Shunsuke
supporting information, p. 6181 - 6185 (2018/05/03)
A new protocol for the deoxygenation of alcohols and the hydrogenation of alkenes under Br?nsted acid catalysis has been developed. The method is based on the use of either a benzyl or isopropyl ether as a traceless hydrogen-atom donor, and involves an intramolecular hydride transfer as a key step, which is achieved in a regio- and stereoselective manner.
TRIMETHYLSILYL TRIFLATE IN ORGANIC SYNTHESIS
Noyori, R.,Murata, S.,Suzuki, M.
, p. 3899 - 3910 (2007/10/02)
Trimethylsilyl triflate is a powerful silylating agent for organic compounds and acts as a catalyst which accelerates a variety of nucleophilic reactions in aprotic media.The reactions proceed via one-center, electrophilic coordination of the silyl group to hetero functional groups and exhibit unique selectivities.