76886-47-0Relevant academic research and scientific papers
Generation of Aldehydic Enol Ethers and Enamines by Olefination of Ketones
Gilbert, John C.,Weerasooriya, Upali
, p. 448 - 453 (2007/10/02)
Reaction of aliphatic ketones with dimethyl (diazomethyl)phosphonate (5, R = CH3) in the presence of alcohols and amines afforded enol ethers and enamines, respectively, of the next higher aldehyde.The technique has been found to be applicable to several
A NOVEL ROUTE TO ALDEHYDIC ENOL ETHERS AND ENAMINES
Gilbert, J. C.,Weerasooriya, U.
, p. 2041 - 2044 (2007/10/02)
Base-promoted reaction of dimethyl diazomethylphosphonate (1) with dialkyl and cyclic ketones in the presence of alcohols and of amines affords aldehydic enol ethers and enamines, respectively.
