76978-41-1

Upstream product

• 105401-84-1 (4E)-5-(4-methoxyphenyl)pent-4-en-1-ol 
• 1308888-10-9 5-(4-methoxycinnamyl)-2,2-dimethyl-1,3-dioxane-4,6-dione 
• 24680-50-0 4-methoxy-trans-cinnamaldehyde 
• 92454-52-9 5-(4-methoxyphenyl)-pent-4-enoic acid ethyl ester 

Downstream Products

• 148020-02-4 (E)-N-Methyl-5-(4-methoxyphenyl)pent-4-enylamine 
• 66162-78-5 1-methyl-2-(4-methoxyphenyl)pyrrolidine 
• 791637-40-6 (±)-6-(4-methoxyphenyl)-2-methyl-3,6-dihydro-2H-pyran 
• 791637-40-6 (±)-(2S,6R)-6-(4-methoxyphenyl)-2-methyl-3,6-dihydro-2H-pyran 
• 49678-07-1 (2E,4E)-5-(4-methoxyphenyl)penta-2,4-dienal 
• 1308888-04-1 (S,E)-5-(4-methoxyphenyl)-3-(nitromethyl)pent-4-enal 

Relevant academic research and scientific papers

Oxidative and enantioselective cross-coupling of aldehydes and nitromethane catalyzed by diphenylprolinol silyl ether

Synthetically important β-substituted γ-nitro aldehydes have been synthesized with excellent enantioselectivity by the cross-coupling reaction of β-aryl substituted aldehydes or Y γ-unsaturated aldehydes and nitromethane using 2,3-dichloro-5,6-dicyanoquinone (DDQ) and diphenylprolinol silyl ether as an oxidant and catalyst, respectively (see scheme; TMS=trimethylsilyl).

Regioselective control in the palladium-catalyzed isomerization of methylenecyclopropylcarbinols using acetic acid as a reagent

Tuning the regioselectivity of the Pd-catalyzed isomerization of methylenecyclopropylcarbinols in acetic acid is achieved by a subtle choice of the ligand and/or solvent. When dioxane is used as the solvent, penta-2,4-dien-1-ols are formed, whereas when A

New Total Synthesis of (+)-N-Methylanisomycin by Anodic Cyclization of δ-Alkenylamine

A chiral total synthesis of (+)-N-methylanisomycin (1a) from L-diethyl tartrate via 15 steps is reported.The key step in the synthesis was a regio- and stereoselective cyclization of (E)-δ-alkenylamine 12a or its (Z)-isomer 12b by anodic oxidation of thei