769922-58-9

Basic information

• Product Name: 2-Pyridinecarbothioic acid, S-phenyl ester
• CAS NO: 769922-58-9
• Molecular Formula: C12H9NOS
• Molecular Weight: 215.276
• Mol File: 769922-58-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Pyridinecarbothioic acid, S-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridinecarbothioic acid, S-phenyl ester(769922-58-9)
• EPA Substance Registry System: 2-Pyridinecarbothioic acid, S-phenyl ester(769922-58-9)

Safety Data

• Hazardous Substances Data: 769922-58-9(Hazardous Substances Data)

Upstream product

• 98-98-6 2-Picolinic acid 
• 108-98-5 thiophenol 
• 1121-60-4 pyridine-2-carbaldehyde 
• 882-33-7 diphenyldisulfane 
• 29745-44-6 pyridine-2-carbonyl chloride 
• 109-06-8 α-picoline 
• 144223-29-0 1H-1,2,3-benzotriazol-1-yl(2-pyridinyl)methanone 

Downstream Products

• 15634-63-6 {PhSFe(CO)3}2 

Relevant articles and documents

Multiplexing of combinatorial chemistry in antimycin biosynthesis: Expansion of molecular diversity and utility

Diversity-oriented biosynthesis of a library of antimycin-like compounds (380 altogether) was accomplished by using multiplex combinatorial biosynthesis. The core strategy depends on the use of combinatorial chemistry at different biosynthetic stages. This approach is applicable for the diversification of polyketides, nonribosomal peptides, and the hybrids that share a similar biosynthetic logic. Copyright

Syntheses of thiol and selenol esters by oxidative coupling reaction of aldehydes with RYYR (Y = S, Se) under metal-free conditions

Thiol and selenol esters were synthesized by a direct oxidative coupling reaction of aldehydes with disulfides or diselenides in ethyl acetate under metal-free conditions. Among the oxidants examined, tert-butyl peroxide (TBP) was shown to give the best results. For the substrates with both electron-donating and electron-withdrawing substituents, the reaction proceeded smoothly and gave moderate to good yields. Compared with the previous method, the present route is very simple, atom-economical and environmentally friendly. This journal is the Partner Organisations 2014.

A new convenient preparation of thiol esters utilizing N-acylbenzotriazoles

Diverse thiol esters were synthesized in good to excellent yields (76-99%) by reactions of thiophenol, benzyl mercaptan, ethyl mercaptoacetate, and mercaptoacetic acid with N-acylbenzotriazoles under mild conditions. These results demonstrate the utility of N-acylbenzotriazoles as mild S-acylating agents, especially when the corresponding acid chlorides are not readily available.