76994-43-9Relevant academic research and scientific papers
NEW SYNTHESIS OF STEROIDAL TETRAHYDROOXAZIN-2-ONES
Schneider,Gyula,Hackler,Laszlo,Sohar,Pal
, p. 3987 - 3996 (2007/10/02)
In the DMSO/NaHCO3 system, 16α-aminomethyl-, 16α-benzylaminomethyl- and substituted benzylaminomethyl-3-methoxy-17β-tosyloxyestra-1,3,5(10)-triene (3, 5a-k) do not undergo oxidation, but form a tetrahydrooxazin-2-one ring (7, 8a-k) via neighboring group p
New synthesis of steroidal tetrahydro-oxazin-2-ones
Schneider, Gyula,Hackler, Laszlo,Dombi, Gyoergy
, p. 891 - 892 (2007/10/02)
In dimethyl sulphoxide-NaHCO3, 16α-aminomethyl- and 16α-benzylaminomethyl-3-methoxy-17β-tosyloxyestra-1,3,5(10)-triene undergo cyclisation into the corresponding tetrahydro-oxazin-2-ones instead of oxidation.
