77001-46-8Relevant academic research and scientific papers
FLUOROCARBON-SELENIUM CHEMISTRY: ACCOMPLISHMENTS AND QUESTS
HAAS, A.
, p. 415 - 440 (2007/10/02)
The binary selenium fluorides SeFn (n = 2, 4, 6) and Se2F2 are considered along with corresponding perfluorohalogenoorganoselenium compounds with selenium in the oxidation states 1, 2, 4 and 6.For lower selenium fluorides, preparation and characterisation are emphasized.Recent results in the chemistry of SeCF2, CF3SeCl, CF3SeSeCF3, CF3Se(O)OM and CF3SeVI-compounds are presented.A comparison with the correspondig sulfur chemistry is also provided.
Syntheses of (Trifluoromethylseleno)phosphoryl Dichloride and Thiocarbonyl Bromide Fluoride
Haas, Alois,Mikolajczak, Jerzy
, p. 829 - 831 (2007/10/02)
In the presence of SbCl5 or BCl3 CF3SeCl reacts with CH3OPCl2 to form CF3SeP(O)Cl2 (1).Halogen exchange reactions of SCFCl occur with OPCl3 or SPBr3 to give OPFnCl3-n or SPClnBr3-n (n = 1-3) as well as SPBrClF.The reaction of SCFCl with PBr3 leads to SCBrF (2).
