77078-74-1

Upstream product

• 23963-14-6 (1S,4R)-4,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,2'-[1,3]dioxolan]-3-one 
• 591-51-5 phenyllithium 

Downstream Products

• 31503-17-0 (-)-(1R,2R,3R,4S)-1,7,7-trimethyl-2-phenyl-bicyclo[2.2.1]heptane-2,3-diol 
• 959696-54-9 2-exo-Hydroxy-2-endo-phenylbornan-3-on 

Relevant academic research and scientific papers

Stereoselektive Synthese von Alkoholen, VI. Asymmetrische Synthesen von 4-Penten-2-ol ueber Allylboronsaeureester chiraler Glycole

Allylboronates 3 of substituted camphor glycols 2 add to acetaldehyde giving 4-penten-2-ol (1).The substituents affect the extent of asymmetric induction in an additive manner.Pentenol of 86percent enantiomeric purity was obtained using 2d as chiral matrix.