77111-99-0Relevant articles and documents
Electrochemical Reduction of Diaryl Trithiocarbonates and Related Compounds
Falsig, M.,Lund, H.,Nadjo, L.,Saveant, J. M.
, p. 685 - 692 (2007/10/02)
Electrochemical reduction of diaryl trithiocarbonates (1) in aprotic medium followed by alkylation gives a mixture of Z- ad E-tetrathioethylenes (2) and thioanisoles (3) in which Z:E ratio is approximately 1:10.The influence of different parameters on the yield of 2 and 3 has been investigated, and these results together with those from a kinetic investigation published elsewhere have been used in a discussion of the reaction mechanism.