77123-18-3

Basic information

• Product Name: (1R,2R)-1,2-dihydrochrysene-1,2-diol
• Synonyms: (1R,2R)-1,2-Dihydrochrysene-1,2-diol; 1,2-chrysenediol, 1,2-dihydro-, (1R,2R)-; 1,2-Chrysenediol, 1,2-dihydro-, trans-(+-)-; trans-(+-)-1,2-Dihydro-1,2-chrysenediol
• CAS NO: 77123-18-3
• Molecular Formula: C₁₈H₁₄O₂
• Molecular Weight: 262.3026
• Mol File: 77123-18-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 525.2°C at 760 mmHg
• Flash Point: 257.2°C
• Density: 1.367g/cm³
• Vapor Pressure: 7.35E-12mmHg at 25°C
• Refractive Index: 1.793
• CAS DataBase Reference: (1R,2R)-1,2-dihydrochrysene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R)-1,2-dihydrochrysene-1,2-diol(77123-18-3)
• EPA Substance Registry System: (1R,2R)-1,2-dihydrochrysene-1,2-diol(77123-18-3)

Safety Data

• Hazardous Substances Data: 77123-18-3(Hazardous Substances Data)

Upstream product

• 80433-96-1 (-)-trans-(1R,2R)-1,2-diacetoxy-1,2-dihydrochrysene 
• 80433-88-1 (+)-trans-(1R,2R)-1,2-dihydroxy-1,2,3,4-tetrahydrochrysene 
• 80433-90-5 (-)-trans-(1R,2R)-1,2-diacetoxy-1,2,3,4-tetrahydrochrysene 
• 101349-52-4 2-oxo-1,2,3,4,11,12-hexahydrochrysene 
• 101349-54-6 acetic acid chrysen-2-yl ester 
• 65945-06-4 2-hydroxychrysene 
• 2304-83-8 1,2-chrysenequinone 
• 66267-15-0 Acetic acid (1S,2S)-2-acetoxy-1,2-dihydro-chrysen-1-yl ester 
• 80399-23-1 ((1R,2S,5R)-2-Isopropyl-5-methyl-cyclohexyloxy)-acetic acid (1R,2R)-2-[2-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-acetoxy]-1,2,3,4-tetrahydro-chrysen-1-yl ester 
• 67175-75-1 (+/-)-trans-1,2-dihydroxy-1,2,3,4-tetrahydrochrysene 
• 80409-34-3 Acetic acid (1R,2R)-2-acetoxy-4-bromo-1,2,3,4-tetrahydro-chrysen-1-yl ester 

Downstream Products

• 64920-33-8 trans-1,2-dihydroxy-syn-3,4-epoxy-1,2,3,4-tetrahydrochrysene 
• 64920-33-8 trans-1,2-dihydroxy-anti-3,4-epoxy-1,2,3,4-tetrahydrochrysene 
• 111901-41-8 trans-7,8-dihydroxy-anti-9,10-epoxy-5-methyl-7,8,9,10-tetrahydrochrysene 
• 77123-23-0 (+)-(1R,2S,3S,4R)-1,2-dihydroxy-3,4-epoxy-1,2,3,4-tetrahydrochrysene 
• 77123-24-1 (-)-(1R,2S,3R,4S)-1,2-dihydroxy-3,4-epoxy-1,2,3,4-tetrahydrochrysene 

Relevant articles and documents

Enantioselective synthesis of (-)-(1R,2R)-1,2-dihydrochrysene-1,2-diol

A general chiral building block containing the 1R,2R-trans-diol moiety was constructed utilizing the stereoselective Shi-epoxidation reaction on a tetralone scaffold assembled by a Negishi cross-coupling on N,N-diethylbenzamide. Further elaboration of thi

Synthesis of the Enantiomeric Bay-Region Diol Epoxides of Benzanthracene and Chrysene

Both trans-3,4-dihydroxy-3,4-dihydrobenzanthracene and trans-1,2-dihydroxy-1,2-dihydrochrysene are known proximate carcinogens of their respective hydrocarbons.The present study describes the synthesis of their (+)- and (-)-enantiomers as well as the d