77131-95-4Relevant academic research and scientific papers
REACTION DU CHLOROALLYLLITHIUM ET DU gem-CHLORO(METHYL)ALLYLLITHIUM SUR LES ESTERS: NOUVELLE METHODE DE SYNTHESE DE CETONES CHLOREES ETHYLENIQUES ET D'ACYLOINES ETHYLENIQUES
Mauze, B.,Doucoure, A.,Miginiac, I.
, p. 1 - 8 (2007/10/02)
Chloroallyllithium and gem-chloro(methyl)allyllithium readily react with aliphatic and aromatic esters to produce α- and γ-chlorinated α- and β-ethylenic ketones, and α-ethylenic acyloins, according to the hydrolysis conditions.
Reaction of 3-Chloroallyltrimethylsilane with Acid Chloride and Exploitation of a New Regioselective Synthesis of αβ-Unsaturated Epoxide
Ochiai, Masahito,Fujita, Eiichi
, p. 4369 - 4372 (2007/10/02)
α-Chloro-βγ-unsaturated ketone (2) was synthetized from the reaction of 3-chloroallyltrimethylsilane (1) with acid chloride.The ketone was converted into αβ-unsaturated epoxide (3) regioselectively in good yield via reduction with NaBH4 or LiAlH4 followed
